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Nanomaterials 2022, 12, 3069 11 of 12 References Supplementary Materials: The following supporting information can be downloaded at: https:// www.mdpi.com/article/10.3390/nano12173069/s1, Figure S1: SEM-EDS of the LAZTP. (a) 10 μm size LAZTP. (b) Zn element content chart; Figure S2: SPL’s GCD at three different current densities; Figure S3: CV test of SPLL under different cycle rates; Figure S4: (a) 50 cycles of LNMO/SPL/Li at 0.1c rate in the greenhouse. (b) The first charge and discharge of LNMO/SPL/Li at different rates; Figure S5: (a,b) Surface map of the SPLL before and after cycle. The SEM cross-sectional view of (c) and (d); Figure S6: Physical image of the surface before and after the SPLL cycle; Figure S7: XRD before and after SPLL cycle; Figure S8: Physical image of the surface before and after the SPLL cycle. SP is an electrolyte membrane formed by stirring and drying three polymers in DMF (among them, DMF 30 mL, PVA 1 g, PES 2 g, PVDF 5% copolymerized base); SPL is added on the basis of SP LiBF4 (PES es:Li = 8:1); SPLL is based on SPL with 10%LAZTP added. Author Contributions: Conceptualization, X.L.; methodology, L.L.; writing—original draft prepara- tion, X.J.; writing—review and editing, S.Z.; supervision, M.H.; formal analysis, D.H. All authors have read and agreed to the published version of the manuscript. Funding: This research was supported by the: Guangxi Natural Science Foundation (No. 2020GXNS- FAA297082), Guangxi Innovation Driven Development Project (No. AA18242036-2), National Natural Science Foundation of China (No. 52161033), Fund Project of the GDAS Special Project of Science and Technology Development, Guangdong Academy of Sciences Program (No. 2020GDASYL- 20200104030), and Fund Project of the Key Lab of Guangdong for Modern Surface Engineering Technology (No. 2018KFKT01). Data Availability Statement: Not applicable. Conflicts of Interest: The authors declare no conflict of interest. The funders had no role in the design of the study; in the collection, analyses, or interpretation of data; in the writing of the manuscript, or in the decision to publish the results. 1. Cheng, X.B.; Zhao, C.Z.; Yao, Y.X.; Liu, H.; Zhang, Q. Recent Advances in Energy Chemistry between Solid-State Electrolyte and Safe Lithium-Metal Anodes. Chem 2019, 5, 74–96. [CrossRef] 2. Ghazi, Z.A.; Sun, Z.H.; Sun, C.G.; Qi, F.L.; An, B.G.; Li, F.; Cheng, H.M. Key Aspects of Lithium Metal Anodes for Lithium Metal Batteries. Small 2019, 15, 1900687–1900714. [CrossRef] [PubMed] 3. Forsyth, M.; Porcarelli, L.; Wang, X.E.; Goujon, N.; Mecerreyes, D. Innovative electrolytes based on ionic liquids and polymers for next-generation solid-state batteries. Acc. Chem. Res. 2019, 52, 686–694. [CrossRef] [PubMed] 4. Choudhury, S.; Stalin, S.; Vu, D.; Warren, A.; Deng, Y.; Biswal, P.; Archer, L.A. Solid-state polymer electrolytes for high-performance lithium metal batteries. Nat. Commun. 2019, 410, 398. [CrossRef] 5. Feng, J.K.; Yan, B.G.; Liu, J.C.; Lai, M.O.; Li, L. All solid state lithium ion rechargeable batteries using NASICON structured electrolyte. Mater. Technol. 2013, 228, 76–279. [CrossRef] 6. Chen, R.; Qu, W.; Guo, X.; Li, L.; Wu, F. The pursuit of solid-state electrolytes for lithium batteries: From comprehensive insight to emerging horizons. Mater. 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Modelling electro-chemical induced stresses in all-solid-state batteries: Anisotropy effects in cathodes and cell design optimisation. J. Power Sources 2021, 489, 229430–229439. [CrossRef] 12. Liang, Y.; Liu, Y.; Chen, D.; Dong, L.; Guang, Z.; Liu, J.; Yuan, B.; Yang, M.; Dong, Y.; Li, Q.; et al. Hydroxyapatite functionalization of solid polymer electrolytes for high-conductivity solid-state lithium-ion batteries. Mater. Today Energy 2021, 20, 100694–100703. [CrossRef] 13. Li, J.H.; Wang, R.G. Recent advances in the interfacial stability, design and in situ characterization of garnet-type Li7La3Zr2O12 solid-state electrolytes based lithium metal batteries. Ceram. Int. 2021, 47, 13280–13290. [CrossRef]PDF Image | Simple Three-Matrix Solid Electrolyte Membrane in Air
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