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Simple Three-Matrix Solid Electrolyte Membrane in Air

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Simple Three-Matrix Solid Electrolyte Membrane in Air ( simple-three-matrix-solid-electrolyte-membrane-air )

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electrolyte and provides a lithium ion migration channel, we analyzed the local chemical s - d e f - e g - L e - e c d Nanomaterials 2022, 12, 3069 environment of lithium ion by 13C solid-state nuclear magnetic resonance (NMR). A shown in Figure 5d, the peaks of SPL are scattered, and there are many impurity peaks In contrast, for SPLL, the peaks near 50 ppm and 140 ppm gradually become sharp, indi cating that the addition of LAZTP and SiO2 reduces the crystallinity of SPLL polymer an enhances the conductivity of the material, which is consistent with the EIS results [26]. SPL and SPLL. SPL and SPLL. Constant current charge and discharge (GCD) were used to evaluate the influence of the addition of LAZTP and SiO on the electrochemical stability of the polymer elec- Constant current charge an2d discharge (GCD) were used to evaluate the influence o trolytes under the current density of 0.05, 0.1 and 0.2 mA cm−2. Figure 6c shows that the the addition of LAZTP and SiO2 on the electrochemical stability of the polymer electro Li/SPLL/Li battery exhibits a stable Li electroplating/stripping under the corresponding lytes under the current density of 0.05, 0.1 and 0.2 mA cm−2. Figure 6c shows that th 8 of 12 Figure 5. (a) Li1s, (b) N1s, and (c) Li1s XPS spectra of the SPL and SPLL. (d) Solid state NMR of the Figure 5. (a) Li1s, (b) N1s, and (c) Li1s XPS spectra of the SPL and SPLL. (d) Solid state NMR of th current density. Moreover, it displays excellent stability even after 1000 cycles of long- Li/SPLL/Li battery exhibits a stable Li electroplating/stripping under the correspondin term plating/stripping, demonstrating a good rate performance. On the contrary, the current density. Moreover, it displays exce−ll2ent stability even after 1000 cycles of long SPL polymer appears flocculent at 0.2 mA cm during the plating/stripping process term plating/stripping, demonstrating a good rate performance. On the contrary, the SP (Figure S2) [27]. Figure 6b shows that the interface impedance increases after the cycling polymer appears flocculent at 0.2 mA cm−2 during the plating/stripping process (Figur test, indicating that a stable SEI film is formed at the interface, reducing the loss at the Nanomaterials 2022, 12, x FOR PEER REVIEW + 9 of 13 Sin2t)er[f2a7c]e. aFnigduimrep6robvsinhgowthse Lthi atrtahnesminitsesirofancreatiem. Apeccdoarndcinegintocrlietaersaetsuraeftrerpothrtes,caydcdling test, in inorganicmetaloxideLAZTP[28]andnon-metaloxideSiO [29]canincreasetheconductiv- dicating that a stable SEI film is formed at the interfa2ce, reducing the loss at the interfac ity and amorphous regio+n of the polymer electrolyte and improve the lithium ion migration. and improving the Li transmission rate. According to literature reports, adding inorgani metal oxide LAZTP [28]and non-metal oxide SiO2 [29] can increase the conductivity an amorphous region of the polymer electrolyte and improve the lithium ion migration. Figure 6. (a) Two-sided photo after GCD cycled 1000 times. (b) impedance spectra before and after Figure 6. (a) Two-sided photo after GCD cycled 1000 times. (b) impedance spectra before and after GCD cycle. (c) GCD cycling of the Li/SPLL/Li cells at 0.05, 0.1 and 0.2 mA cm−2. GCD cycle. (c) GCD cycling of the Li/SPLL/Li cells at 0.05, 0.1 and 0.2 mA cm−2. To evaluate the electrochemical stability of the electrolytes, the LNMO/SPLL/Li and LNMO/SPL/Li batteries were assembled with SPLL and SPL electrolyte membranes, re- spectively [30]. Figure 7a,d shows the rate performance of the two batteries at 0.1 C, 0.2 C,

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