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• Liquid fuel conversion: cooled and cleaned syngas can be converted to various liquid fuels using the Fischer-Tropsch process, a series of chemical reactions occurring from introduction of a catalyst to the syngas • Energy storage: syngas can be stored for later use or transferred to another location. The syngas is the only direct output of the gasification process. If the syngas is combusted, in the various methods described above, the resulting emissions must be monitored and maintained below EPA levels, and is not typically an issue. Table 23 shows the EPA standards of syngas combustion emissions. Local standards, such as the strict nitrogen oxide NOx limit of California’s San Joaquin Valley Air Pollution Control District, may require additional emissions control systems to be used (Walt 2010). Table 23. Example of Syngas combustion emissions (Source: Lauber 2006) EPA Standard Princeton versus EPA Item Tested Particulate CO Hydrocarbon (HC) NOx Sulfur Dioxide (SO2) Hydrochloric Acid HCI Chlorine (Cl2) + HCI Mercury (Hg) Dioxin Furan Opacity Location Stack Stack Stack Stack Stack Stack Stack Stack Stack Test Result 0.0014 32.2 Not Detectable 66.81 15.88 12.068 9.068 0.0081 0.098 10% Unit gr/dscf ppmv ppmv ppmv ppmv ppmv ppmv ug/m3 ngTEQ/dscm 0.0015 10% lower 100 60% lower 10 99% lower 150 60% lower 30 50% lower 25 50% lower 21 60% lower 8.1 99% lower 0.11 10% lower 10% Same The gasification facility collects revenue from several possible sources. Tipping fees are paid to the WTE facility for disposal of the MSW. The energy produced, in the form of electricity, syngas, or liquid fuels can be sold immediately upon production or stored for later use or sale. The terms for selling the energy product(s) vary and may include combinations of electricity, syngas, liquid fuels, or storage options. The residual material may be marketed as well, particularly vitrified slag from high-temperature gasification. Residual Materials Characteristics of residual materials vary depending on the temperature level for the respective gasification processes. At low temperatures (below the melting point for inorganic components of the feedstock), the residual material is bottom ash and can be reused as a building material or sent to a landfill. At higher temperatures, the inorganic material flows from the gasification chamber in a molten state. This vitrified slag is cooled and processed for reuse, typically as a 122PDF Image | 4th Annual Chena Renewable Energy Fair
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