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Minerals 2021, 11, 1330 16 of 23 Figure 11. Variation diagram of Br ion concentration in igneous rock static immersion experiment. The I and B contents in the solution were low with little fluctuation, but the saline The I and B contents in the solution were low with little fluctuation, but the saline fluid more easily activated the ions (Figures 12 and 13). Moreover, the activation effect fluid more easily activated the ions (Figures 12 and 13). Moreover, the activation effect of of the 2 mol/L NaCl solution was better than that of the 1 mol/L NaCl solution; it was the 2 mol/L NaCl solution was better than that of the 1 mol/L NaCl solution; it was gen- generally 1~2 times higher (Table 4). erally 1~2 times higher (Table 4). Minerals 2021, 11, 1330 Figure 12. Variation diagram of I ion concentration in igneous rock static immersion experiment. 17 of 24 Figure 13. Variation diagram of B ion concentration in igneous rock static immersion experiment. Figure 13. Variation diagram of B ion concentration in igneous rock static immersion experiment. Theaboveanalysis showsthatsalliinefflluiidwaassmoorreeccoonndduucicviveetotoththeeacatcitviavtaiotinonofof vvaarrioioussiioonss,,eesspeciiallyinthe2mol/LNaaCllssoolulutitoionn,,whhilieleththeesosolulutitoinonwwithithwweaekakacaicdid waasscconducivetottheddisissoolulutitoionnofoKf.KL.iLwiawsansotndoitssdoilsvseodlviendthinewthheowleheoxlpeereixmpenrtim,ine-nt, inddiciactaintigngthtahtathtehesosolulutitoinoncocnocnecnetnrtartaiotinonwwasasnontothtehefafcatcotrorafaffefcetcintigngthtehedidsissosloultuiotinonofof lithium, and the main controlling factor was temperature. Under the same conditions, the lithium, and the main controlling factor was temperature. Under the same conditions, the solubility of K in the NaCl solution was approximately 1~2 orders of magnitude higher solubility of K in the NaCl solution was approximately 1~2 orders of magnitude higher than than that in the distilled water. Potassium in basalt is more easily dissolved than that in that in the distilled water. Potassium in basalt is more easily dissolved than that in granite, granite, which further reveals that the water–rock reaction between basalt and basin which further reveals that the water–rock reaction between basalt and basin brine with brine with weak alkalinity can provide the source of ore-forming materials for potassi- weak alkalinity can provide the source of ore-forming materials for potassium-rich brines. um-rich brines. 5.3.2. Influence of Time on the Igneous Rock Water–Rock Reaction formation of brine ore takes a long time. 5.3.2. Influence of Time on the Igneous Rock Water–Rock Reaction The trends of dissolution of Ca, K, Sr, and Li elements in basalt and granite are the same,TwheithtreansdmsaollfflduiscstoulautionaonfdCoa,bKvi,oSurs, apnodsitLivielceomrreenltastionnb(aFsiaglutraen1d4g).raUnnitdeearrceetrhtaein csoanmdeit,iwonitsh,MasgminallgfrlauncittueaitsiocnorarnedlaotebdviwouitshpSo,switihvielecoMrrgeliantiboans(aFltigiusrnee1g4a)t.iUvenldyecrocrerretlaitned wcoitnhdCitaio,nKs,MSrg,aindgrLain.itTehisecmorarxeilmateudmwditihssSo,luwthioilneaMmgoiunnbtassoalftKis,nLeig,aMtigv,elCyac,oarnredlaSteadre rweaictheCdaa,fKte,rS3r,hanodfrLeia.cTtihoen,maanxdimthuemmdaixssimolutmiondiasmsoolutnitosnoafmKo,uLni,tMofgK,C,Ma,ga,nSd,aSnadreBr inregacrhanediteafitsere3ahchoefdreafctteiron5,hanodftrheeacmtiaoxnim(Fuimgudreis1so4l)u.tTiohnearmesouulnttooffthKi,sMrega,cSt,ioandisBqruinite dgirffaenrietentisfroemachthedataoftfetrh5ehbroifnreascatmiopnle(Fsiginurtehe14J)ia.nTghleinregsuBlatsoinf,thwishricehacitniodniciastqesuitheadtitfh-e foferrmenatiofrnomof bthrainteoofrtehteakbersinaelosanmgptilmese.in the Jiangling Basin, which indicates that thePDF Image | Origin of Lithium Potassium Rich Brines in the Jianghan
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