Ion Enrichment inside Ultra-Short Carbon Nanotubes

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Ion Enrichment inside Ultra-Short Carbon Nanotubes ( ion-enrichment-inside-ultra-short-carbon-nanotubes )

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Nanomaterials 2022, 12, 3528 duration. The wider MWCNTs showed more effective truncation than the thinner MWCNTs, which was consistent with the results shown in Figure 2a–e. at intervals of 0.1 μm. Figure 2e shows the statistical analysis results of the 6 nm-wide MWCNTs and the 20–50 nm-wide MWCNTs. Increasing the ball-milling duration from 6 to 24 h resulted in an increase in the proportion of shorter CNTs. Figure 2f shows that the average lengths of both kinds of MWCNTs decreased significantly with the ball milling Figure 2. Ball milling treatment results of two kinds of CNTs. Transmission electron microscopy Figure 2. Ball milling treatment results of two kinds of CNTs. Transmission electron microscopy (TEM) images of the 6 nm-wide multi-walled carbon nanotubes (MWCNTs) before (a) and after (b) (TEM) images of the 6 nm-wide multi-walled carbon nanotubes (MWCNTs) before (a) and after 24 h ball milling treatment and acid pickling. Figures (c) and (d) display the TEM images of 20–50 (b) 24 h ball milling treatment and acid pickling. Figures (c) and (d) display the TEM images of nm-wide MWCNTs before and after 24 h ball milling treatment and acid pickling, respectively. The 20–50 nm-wide MWCNTs before and after 24 h ball milling treatment and acid pickling, respectively. upper and lower images in (e) display the length statistical analysis results of the 6 nm-wide The upper and lower images in (e) display the length statistical analysis results of the 6 nm-wide MWCNTs and the 20–50 nm-wide MWCNTs, respectively. (f) Average lengths of both kinds of MWCNTs and the 20–50 nm-wide MWCNTs, respectively. (f) Average lengths of both kinds of MWCNTs plotted against ball milling time. 4 of 13 MWCNTs plotted against ball milling time. The effects of the different ball milling durations on the lengths of CNTs were also Acid pickling is a common method used to remove the impurities inside CNTs investigated. For each kind of the CNTs that were ball milled using a certain duration, [13,14,39]. Figure 3a–c shows the TEM images of three kinds of common blockages in the lengths of about 50 random CNTs were measured. These CNTs had lengths ranging mid-section of the raw long CNTs, namely residual catalyst materials, amorphous from 0.05 to 1.1 μm, therefore, the numbers of CNTs with different lengths were counted graphite and internal defects. After the ball milling and acid picking treatment, these at intervals of 0.1 μm. Figure 2e shows the statistical analysis results of the 6 nm-wide blockages were efficiently removed. As shown in Figure 3d, the ultra-short CNTs were MWCNTs and the 20–50 nm-wide MWCNTs. Increasing the ball-milling duration from unobstructed. 6 to 24 h resulted in an increase in the proportion of shorter CNTs. Figure 2f shows that the average lengths of both kinds of MWCNTs decreased significantly with the ball milling duration. The wider MWCNTs showed more effective truncation than the thinner MWCNTs, which was consistent with the results shown in Figure 2a–e. Acid pickling is a common method used to remove the impurities inside CNTs [13,14,39]. Figure 3a–c shows the TEM images of three kinds of common blockages in mid-section of the raw long CNTs, namely residual catalyst materials, amorphous graphite and internal defects. After the ball milling and acid picking treatment, these blockages were efficiently removed. As shown in Figure 3d, the ultra-short CNTs were unobstructed.

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