Flexible Zn-Based Batteries with Polymer Electrolyte

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Flexible Zn-Based Batteries with Polymer Electrolyte ( flexible-zn-based-batteries-with-polymer-electrolyte )

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ibility between MXene and the polymeric matrix, which enabled the PVHF/MXene-g- PMA to deliver high ionic conductivity of 2.69 × 10−4 S cm−1 at room temperature (Figure 6a). Benefitting from the solvent-free characteristics and compatible interface, the assem- bled all-solid state ZIB exhibited stable electrochemical performance that could operate in Batteries 2022, 8, 59 a wide temperature range from −35 °C to 100 °C without HER. No obvious capacity loss was observed after being stored at low or high temperatures. 10 of 17 Figure 6. (a) Schematic fabrication of the solid state MXene-g-PMA electrolyte. Reproduced with Figure 6. (a) Schematic fabrication of the solid state MXene-g-PMA electrolyte. Reproduced with per- permission from [59]. (b) The reaction mechanism of the 1,3-dioxolane based solid polymer electro- mission from [59]. (b) The reaction mechanism of the 1,3-dioxolane based solid polymer electrolytes. lytes. Reproduced with permission from [60]. Reproduced with permission from [60]. The in situ constTruhcetinonsitmu ecothnostdrufcotriosnomlidet-hsotadtefobrastotleidri-estsacteanbaettfefericetsivcaenlyefrfedctuivcelyinrteedru-ce interfa- cial impedance and voltage polarization of flexible/wearable batteries, leading to higher facial impedance and voltage polarization of flexible/wearable batteries, leading to higher Coulombic efficiency. For instance, Ma et al. fabricated an amorphous poly(1,3-dioxolane)- Coulombic efficiency. For instance, Ma et al. fabricated an amorphous poly(1,3-diox- based solid electrolyte through in situ polymerization, which was able to deliver an ultra- olane)-based solid electrolyte through in situ polymerization, which was able to deliver high ionic conductivity of 19.6 mS cm−1 at room temperature, as shown in Figure 6b [60]. an ultrahigh ionic conductivity of 19.6 mS cm−1 at room temperature, as shown in Figure The resultant zinc symmetric battery could reversibly charge/discharge over 1800 h cycles 6b [60]. The resultant zinc symmetric battery could reversibly charge/discharge over 1800 without dendrite growth. The assembled ZIBs based on the in-situ-formed polymer elec- h cycles without dendrite growth. The assembled ZIBs based on the in-situ-formed poly- trolytes could work stably with high capacity retention of 98% after 2000 bending cycles. mer electrolytes cTohueldevwolourtikonstoafbqlyuawsii-tsholhidi-gshtacteapZaIBcsittyorleiqtuenidt-iforneeoafll9-s8o%lida-fstearte2b0a0t0tebriensdminaygprovide a cycles.Theevoluptriomniosifnqgusoalsui-tisonlitdo-tshteatoeccZuIrBresntcoeolifqzuinidc-dferenedraitlel-ssaonlids-isdtea-treabcatitotenrsiteosamchaieyvereliable flexible batteries. 4. Interaction between Electrodes and Polymer Electrolytes Due to its intrinsic electrochemical stability, metallic Zn can be used directly as the anode for Zn-based batteries. However, during the charging process, rough and irregular zinc dendrites are easily formed, which may cause short-circuiting. Moreover, some side- reactions which originate from aqueous solution, including hydrogen evolution reactions (HERs), corrosion, and surface passivation, can seriously affect the stability of the Zn anode. For the cathode of Zn-based batteries, the dissolution of some active materials and the formed electronically insulating electrode-electrolyte interface layers, which are normally referred to the SEI layers, affects the battery performance of Zn-based batteries with respect to capacity, rate capability, cyclic life, and so on [61,62]. In the following section, research into the effects of the interaction between electrodes and polymer electrolytes will be briefly discussed, with a view to providing new perspectives for improving the performance stability of Zn-based batteries.

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Salt water or brine are huge sources for lithium. Most of the worlds lithium is acquired from a brine source. It's even in seawater in a low concentration. Brine is also a byproduct of huge powerplants, which can now use that as an electrolyte and a huge flow battery (which allows storage at the source).

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