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temperature. This means, that more heat can be recovered, thereby increasing the electric power produced from a given heat source. 1.7.1 Organic working fluid classification A characteristic that must be considered during the selection of a fluid is its saturation vapour curve. The degree to which fluids are drying or wetting is generally related to the vibrational degree of freedom available to the fluid molecule. This characteristic affects the fluid applicability, cycle efficiency, and arrangement of associated equipment in a power generation system. Water is a wetting fluid, its vapour saturation curve has a negative slope (δT/δs < 0), resulting in a two-phase mixture upon isentropic expansion. Most organic fluids show, to varying degrees, drying behaviour resulting in a superheated vapour upon isentropic expansion. It is the drying behaviour of organic working fluids that make them superior to water for the utilization of low-temperature thermal resources and are the selected type of refrigerants for further analysis. The working fluid can be classified into three categories. Those are dry, isentropic and wet, depending on the slope of the T-s curve. A dry fluid has a positive slope; a wet fluid has a negative slope; while an isentropic fluid has an infinitely large slope. The shape of the temperature-entropy diagram gives a clear indication of the type of working fluid. Figure 13 T-S diagram for dry fluids (Pentane) 13PDF Image | study of ORC with the expansion process twin screw machines
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