DOE Solar Energy Technologies Program

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DOE Solar Energy Technologies Program ( doe-solar-energy-technologies-program )

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Equivalent NREL Exposure 1000 1 2 3 4 5 6 7 8 9 10 11 12 95 90 85 SPA/GE TSE 392-C ADH SPA/GE D1-SEA210B ADH SPA/KRAFFT SILKRAF ADH SPA/DOW Q3-6093 ADH PIL/GE TSE392-C ADH PILS/GE D1-SEA210B ADH PIL/KRAFFT SILKRAF ADH PIL/DOW Q3-6093 ADH 80 0.0 3.3 6.7 10.0 13.3 16.7 20.0 23.3 26.6 30.0 33.3 36.6 40.0 Total UV Dose (100 X MJ/m2) Trough mirrors (used in commercial solar plants) manufactured by Flabeg, which use silvered, thick, slumped glass with a proprietary multilayer paint system designed for outdoor exposure, have been very durable. Flabeg recently converted its mirror line to the copper-free process and a new lead- free paint system. The manufacturer reports durability is expected to be equivalent. Side-by- side exposure testing began in FY 2004. After 1 year of accelerated and outdoor exposure, new mirrors are performing slightly better than the original mirrors. Equivalent NREL Exposure Time 1000 3 (6 )9 12 15 18 21 24 95 90 85 0.0 10.0 20.0 30.0 40.0 50.0 59.9 69.9 79.9 Total UV Dose (100 x MJ/m2) APS FLA NREL WOM Fig. 1. Loss of solar-weighted reflectance of original Flabeg thick-glass mirrors as function of accelerated WOM and outdoor exposure at Phoenix, AZ (APS), Miami, FL (FLA), and Golden, CO (NREL) in total UV dosage. Testing of samples of Pilkington (4-mm copper- free) mirrors and “Spanish” (Cristaleria Espanola S.A) glass mirrors (3 mm, copper-free, and lead- free paint), bonded to steel with four different candidate adhesives, was initiated in FY 2001 for possible use at Solar Tres. Neither Pilkington nor Spanish mirrors exposed outdoors show degradation after 60 months, but in accelerated testing using the Altas Ci5000 WeatherOmeter (WOM), the Pilkington mirrors exhibit better optical durability, and adhesive-related degradation is more prevalent with Spanish glass mirrors. Spanish mirrors degraded 19.0%, whereas Pilkington mirrors degraded 6.8% after 40 months of accelerated WOM exposure. Depending on the adhesive used to bond the mirror, Spanish mirrors degraded 5.3% to 12.0%, whereas Pilkington mirrors degraded 2.5% to 2.9% after 34 months of accelerated WOM exposure. Fig. 2. Loss of solar-weighted reflectance of thick Pilkington and Spanish reflectors with copper-free back layer, Pb-free paint, and four adhesives as a function of WOM exposure. Thin-glass mirrors also use traditional wet-silvered processes on thin (<1 mm), relatively lightweight glass. Choice of adhesive has been observed to affect the performance of weathered thin-glass mirrors, and corrosion has been observed in deployed mirrors. A matrix of sample constructions has been prepared to identify the most promising combinations of paints and adhesives for use with solar reflectors. After almost two years of exposure in the WOM and in damp heat, data indicate that the mirror performance strongly depends on the back protection. For the copper-free constructions, the addition of epoxy and polyurethane back protection appears to be a poor choice because when these constructions failed, they typically failed catastrophically (e.g., delaminated). Between the mirrors incorporating the new copper- free process, the Glaverbel mirror tended to outperform the Naugatuck mirror. However, this could be because at the time the mirrors were acquired Glaverbel had more experience than Naugatuck in manufacturing mirrors with the copper-free technique. In this experiment, adhesives and substrates were less significant than the choice of back protection. The 3M 504 adhesive and aluminum steel showed slight advantages versus other adhesive/substrates. Edge protection and substrate and glass back- cleaning had no effect. Degradation of the samples exposed to date in the damp-heat chamber is similar, but at a rate ten times faster than observed for samples in the WOM. CPV manufacturers have expressed significant concern regarding the durability of thin-glass mirrors made with copper-free and lead-free paint systems. Solar Thermal R&D Concentrating Solar Power 121 % Hemispherical Reflectance % Hemispherical Reflectance

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