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SEPARATION OF LITHIUM FROM BRINES

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SEPARATION OF LITHIUM FROM BRINES ( separation-lithium-from-brines )

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The data listed in Table 3.5 enlightens the effect of variables in lithium manganese oxide synthesis on adsorbent capacity. It can be deduced that the most effective variables are the oven temperature and Li/Mn ratio. The next effective variable is gel/water ratio in autoclave. The effect of autoclave temperature has the smallest effect on capacity values. After the effect of each variable was roughly determined, a detailed experimental investigation was held to identify the effect of each individual variable by additional experiments. First, the effect of oven temperature was examined as shown in Table 3.6. Table 3.6 Effect of oven temperature on capacity of adsorbents synthesized by Hydrothermal-1 procedure Adsorbent synthesis conditions Adsorption process conditions Oven Autoclave Initial Li Final Li Capacity temperature Gel/water temperature Li/Mn concentration concentration pH (𝐦𝐠𝐋𝐢) o ratio o fraction 𝐠𝐚𝐝𝐬. ( C) 350 450 650 750 ( C) 1 120 1 120 1 120 1 120 (ppm) (ppm) 4 5 3.52 10.1 6.53 4 5 2.59 10.1 11.78 4 5 2.22 10.1 13.34 4 5 3.65 10.1 6.48 Table 3.6 shows that as oven temperature increases, the capacity value of the adsorbent also increases up to 650 oC. After that a lower capacity value was acquired at 750 oC. It is known that the thermodynamic equilibrium for spinel manganese oxide is established around 450-550 oC [94]. Therefore at 750 oC, the crystal structure may be distorted and the capacity values get decreased. Second, the effect of gel water ratio in autoclave was investigated and the results were tabulated in Table 3.7. . 48

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