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SEPARATION OF LITHIUM FROM BRINES

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SEPARATION OF LITHIUM FROM BRINES ( separation-lithium-from-brines )

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Table 1.11 (continued) p-tert- Butylphenol/benzene 1.5.2 Adsorption 0.012 0.0089 0.008 0.012 1.35 1.50 1.0 Separation of lithium via adsorption method is the most convenient technique to be integrated in conventional lithium production processes which are evaporation and precipitation. However, there is no industrial application of adsorption method contemporarily. In this method, simply lithium ions are separated selectively from aqueous solutions through physical or chemical adsorption. Research on adsorbents focuses mostly on alumina and manganese oxide up to now. The usage of alumina was first investigated by Goodenough in 1960 [54]. According to this study, when aluminum chloride or aluminum hydroxide mixed with neutral or basic water, it combines with lithium ions and precipitates in the form of a gel as aluminium hydroxide. After that, lithium was separated from alumina by various solvents and purified. The patents written by the followers of Goodenough claimed that brines including high concentration of calcium and magnesium showed the optimum separation values at 81 oC and pH value of 6.8 [55]. The separation factors and optimum values change with brine source and physical conditions, also in these studies separation of lithium from the precipitated gel was done by high temperature water. In Salton Sea, lithium was separated via alumina adsorbents and 99 % of lithium was recovered from the brine but the process was found to be too expensive. The alumina adsorption was investigated by many scientists with different brines. In 1986, Rothbaum et al. studied the lithium recovery from waste water of a geothermal energy plant by alumina in order to minimize the effect of lithium content on the environment [56]. According to the study, after the separation of silica from water, sodium aluminate was added to the water and at pH equals to 10, gelation occurs. After that, the gel was washed with 60 oC water and the remaining gel was recovered by washing it with sodium hydroxide solution. Unfortunately the purity of the 18

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Product and Development Focus for Infinity Turbine

ORC Waste Heat Turbine and ORC System Build Plans: All turbine plans are $10,000 each. This allows you to build a system and then consider licensing for production after you have completed and tested a unit.

Redox Flow Battery Technology: With the advent of the new USA tax credits for producing and selling batteries ($35/kW) we are focussing on a simple flow battery using shipping containers as the modular electrolyte storage units with tax credits up to $140,000 per system.

Our main focus is on the salt battery. This battery can be used for both thermal and electrical storage applications.

We call it the Cogeneration Battery or Cogen Battery.

One project is converting salt (brine) based water conditioners to simultaneously produce power.

In addition, there are many opportunities to extract Lithium from brine (salt lakes, groundwater, and producer water).

Salt water or brine are huge sources for lithium. Most of the worlds lithium is acquired from a brine source. It's even in seawater in a low concentration. Brine is also a byproduct of huge powerplants, which can now use that as an electrolyte and a huge flow battery (which allows storage at the source).

We welcome any business and equipment inquiries, as well as licensing our turbines for manufacturing.

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