Patent Lithium Extraction with coated ion exchange particles

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Patent Lithium Extraction with coated ion exchange particles ( patent-lithium-extraction-with-coated-ion-exchange-particles )

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17 18 US 10,695,694B2 70um,lesthanabout80um,lesthanabout90um,les 0.7,0.8,0.9,1,2,3,4,5,6,7,8,9,and10.Insome thanabout10um,lesthanabout1,0um,lesthanabout embodiments,xandyisindependentlyselectedfrom0.1, 10,0um,lesthanabout10,0um,morethanabout10 0.2,0.3,0.4,0.5,0.6,0.7,0.8,0.9,1,2,3,4,5,6,7,8,9, um,morethanabout20um,morethanabout30um,more and10.Insomeembodiments,anionexchangematerial thanabout40um,morethanabout50um,morethanabout 5 comprises LiFePO4, Li,SnOz, LiMn03, LiTi03, 60um,morethanabout70um,morethanabout80um, LiTis012,LiMn3012,Li1.6Mn1.604,solid solutions morethanabout90um,morethanabout100um,morethan thereof,orcombinationsthereof. about1,0um,morethanabout10,0um,fromabout1 Insomeembodiments,theionexchangematerialissyn umtoabout10,0um,fromabout1umtoabout1,0um, thesizedbyamethodsuchashydrothermal,solvothermal, fromabout1umtoabout10um,fromabout1umtoabout10sol-gel,solidstate,molten saltflux,ionexchange,micro 80um,fromabout1umtoabout60um,fromabout1um wave,balmiling,chemicalprecipitation,co-precipitation, toabout40um,orfromabout1um about20um.Insome vapordeposition,orcombinationsthereof.Insomeembodi embodiments,thecoatedionexchangeparticleshavean ments,theionexchangematerialissynthesizedbyamethod averagesizeoflesthanabout10um,lesthanabout1,0 suchaschemicalprecipitation,hydrothermal,solidstate, um,orlesthanabout10,0um.Insomeembodiments,the 15microwave,orcombinationsthereof. coatedionexchangeparticlesaresecondaryparticlescom Insomeembodiments,theionexchangematerialsare prisedofsmalerprimaryparticles,whereinthesecondary synthesizedinalithiatedstatewithasub-laticefulyor particleshaveanaveragediameteroflesthanabout10um, partlyocupiedbylithiumions.Insomeembodiments,the lesthanabout20um,lesthanabout30um,lesthanabout ionexchangematerialsaresynthesizedinahydratedstate 40um,lesthanabout50um,lesthanabout60um,les20withasub-laticefulyorpartlyocupiedbyhydrogenions. thanabout70um,lesthanabout80um,lesthanabout90 ParticleSizeofUncoatedIonExchangeParticlesinPorous um,lesthanabout10um,lesthanabout1,0um,les Structure thanabout10,0um,lesthanabout10,0um,more Insomeembodiments,theuncoatedionexchangeparticle thanabout10um,morethanabout20um,morethanabout hasanaveragediameteroflesthanabout10nm,lesthan 30um,morethanabout40um,morethanabout50um,25about20nm,lesthanabout30nm,lesthanabout40nm, morethanabout60um,morethanabout70um,morethan lesthanabout50nm,lesthanabout60nm,lesthanabout about80um,morethanabout90um,morethanabout10 70nm,lesthanabout80nm,lesthanabout90nm,les um,morethanabout1,0um,morethanabout10,0um, thanabout10nm,lesthanabout1,0nm,lesthanabout fromabout1umtoabout10,0um,fromabout1umto 10,0nm,lesthanabout10,0nm,morethanabout10 about1,0um,from about1um toabout10um,from 30nm,morethanabout20nm,morethanabout30nm,more about1umtoabout80um,fromabout1umtoabout60um, thanabout40nm,morethanabout50nm,morethanabout fromabout1umtoabout40um,orfromabout1umto 60nm,morethanabout70nm,morethanabout80nm, about20 morethanabout90nm,morethanabout10nm,morethan Inanembodiment,theaveragediameterofthecoatedion about1,0nm,morethanabout10,0nm,fromabout1 exchangeparticlesortheaveragediameterofcoatedion35nmtoabout10,0nm,fromabout1nmtoabout1,0nm, exchangeparticleswhicharesecondaryparticlescomprised fromabout1nmtoabout10nm,fromabout1nmtoabout ofsmalerprimaryparticles,isdeterminedbymeasuringthe 80nm,fromabout1nmtoabout60nm,fromabout1nm particlesizedistributionofthecoatedionexchangeparticles toabout40nm,orfromabout1nmtoabout20nm.Insome orthecoatedionexchangeparticleswhicharesecondary embodiments,theuncoatedionexchangeparticleshavean particlescomprisedofsmalerprimaryparticles,anddeter-40averagesizeoflesthanabout10nm,lesthanabout1,0 miningthemeanparticlesize. nm,orlesthanabout10,0nm.Insomeembodiments,the Uncoated Ion Exchange Particles in Porous Structure uncoated ion exchange particles are secondary particles Inanaspectdescribedherein,uncoatedionexchange comprisedofsmalerprimaryparticles,whereinthesecond particlesareembeddedin,adheredto,orotherwisesup aryparticleshaveanaveragediameteroflesthanabout10 portedbythestructuralsuport. 45 nm,lesthanabout20nm,lesthanabout30nm,lesthan IonExchangeMaterialofUncoatedIonExchangeParticles about40nm,lesthanabout50nm,lesthanabout60nm, inPorousStructure lesthanabout70nm,lesthanabout80nm,lesthanabout Insomeembodiments,theionexchangematerialissuit 90nm,lesthanabout10nm,lesthanabout1,0nm, ableforhighlithiumabsorptioncapacityandforlithium lesthanabout10,0nm,lesthanabout10,0nm,more ionsinaliquidresourcerelativetootherionssuchassodium 50thanabout10nm,morethanabout20nm,morethanabout ionsandmagnesiumions.Insomeembodiments,theion 30nm,morethanabout40nm,morethanabout50nm, exchangematerialissuitableforstronglithiumionuptakein morethanabout60nm,morethanabout70nm,morethan liquidresourcesincludingthosewithlowconcentrationsof about80nm,morethanabout90nm,morethanabout10 lithiumions,facileelutionoflithiumionswithasmal nm,morethanabout1,0nm,morethanabout10,0nm, excessofacid,andfastionicdifusion. 5fromabout1nm toabout10,0nm,fromabout1nm to Insomeembodiments,theionexchangematerialcom about1,0nm,fromabout1nmtoabout10nm,from prisesanoxide,aphosphate,anoxyfluoride,afluorophos about1nmtoabout80nm,fromabout1nmtoabout60nm, phate,orcombinationsthereof.Inafurtherembodiment,the fromabout1nmtoabout40nm,orfromabout1nmto ionexchangematerialcomprisesLiFePO4,LiMnPO4, about20nm. Li_MO,(M=Ti,Mn,Sn),LiMn0,2,LiTis012,LiMn04,60 Insomeembodiments,theuncoatedionexchangeparticle Li1.6Mn04,LIMO,(M=A1,Cu,Ti),LiTi04,LiTi,1024, hasanaveragediameteroflesthanabout10um,lesthan Li2V04LiSiz0,LiCup,O,Al(OH)3,LiCl.xAl about20um,lesthanabout30um,lesthanabout40um, (OH)3.yH,O,SOxSb.03.yH,O,TiOxSb2O3.yH,O, lesthanabout50um,lesthanabout60um,lesthanabout solidsolutionsthereof,orcombinationsthereof.Insome 70um,lesthanabout80um,lesthanabout90um,les embodiment,xisselectedfrom 0.1,0.2,0.3,0.4,0.5,0.6,65 thanabout10um,lesthanabout1,0um,lesthanabout 0.7,0.8,0.9,1,2,3,4,5,6,7,8,9,and10.Insome 10,0um,lesthanabout10,0um,morethanabout10 embodiments,yisselectedfrom0.1,0.2,0.3,0.4,0.5,0.6, um,morethanabout20um,morethanabout30um,more

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