Patent Lithium Extraction with coated ion exchange particles

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Patent Lithium Extraction with coated ion exchange particles ( patent-lithium-extraction-with-coated-ion-exchange-particles )

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15 16 US 10,695,694B2 lesthanabout800°C.Insomeembodiments,thefreshly ments,theionexchangematerialissynthesizedbyamethod coatedionexchangematerialisheatedtoatemperatureof suchaschemicalprecipitation,hydrothermal,solidstate, morethanabout100°C.,morethanabout20°C.,more microwave,orcombinationsthereof. thanabout30°C.,morethanabout40°C.,morethan Insomeembodiments,theionexchangematerialsare about50°C.,morethanabout600°C.,morethanabout 5 synthesizedinalithiatedstatewithasub-laticefulyor 700°C.,ormorethanabout800°C.Insomeembodiments, partlyocupiedbylithiumions.Insomeembodiments,the thefreshlycoatedionexchangematerialisheatedtoa ionexchangematerialsaresynthesizedinahydratedstate temperaturefromabout10°C.toabout80°C.,fromabout withasub-laticefulyorpartlyocupiedbyhydrogenions. 200°C.toabout800°C.,fromabout300°C.toabout700° Insomeembodiments,theionexchangematerialandthe C.,fromabout40°C.toabout70°C.,fromabout50°C.10coatingmaterialformoneormoreconcentrationgradients toabout700°C.,fromabout10°C.toabout300°C.,from wherethechemicalcompositionofthecoatedionexchange about200°C.toabout400°C.,fromabout30°C.toabout particlevariesbetweentwoormorecompositions.Insome 500°C.,fromabout40°C.toabout600°C.,fromabout embodiments,thechemicalcompositionvariesbetwenthe 500°C.toabout70°C.,orfromabout600°C.toabout ionexchangematerialsandthecoatinginamannerthatis 800° C. In some embodiments, the freshly coated ion 15 continuous,discontinuous,orcontinuousand discontinuous exchangematerialisheatedinanatmosphereofaircom indiferentregionsofthecoatedionexchangeparticle.In prisingoxygen,nitrogen,hydrogen,argon,orcombinations someembodiments,theionexchangematerialsandthe thereof.Insomeembodiments,thefreshlycoatedion coatingmaterialsformaconcentrationgradientthatextends exchangematerialisheatedforatimeperiodoflesthan overathicknesoflesthan1nm,lesthan10nm,lesthan about1hour,lesthanabout2hours,lesthanabout4hours,20 10nm,lesthan1,0nm,lesthan10,0nm,lesthan lesthanabout8hours,lesthanabout24hours,morethan 10,0nm,morethan1nm,morethan10nm,morethan 1hour,morethan2hours,morethan4hours,morethan8 10nm,morethan1,0nm,morethan10,0nm,from hours,fromabout0.5hourstoabout24hours,fromabout about1nmtoabout10,0nm,fromabout10nm,toabout 0.5hourstoabout8hours,fromabout0.5hourstoabout4 10,0nm,orfromabout100toabout1,0nm. hours, from about 0.5 hours to about 2 hours, or from about 25 Particle Size of Coated Ion Exchange Particles in Porous 0.5 hours to about 1hour. Structure Insomeembodiments,thecoatingmaterialisdeposited Insomeembodiments,thecoatedionexchangeparticle withphysicalcharacteristicssuchascrystaline,amorphous, hasanaveragediameteroflesthanabout10nm,lesthan fulcoverage,partialcoverage,uniform,non-uniform,or about20nm,lesthanabout30nm,lesthanabout40nm, combinationsthereof.Insomeembodiments,multiplecoat-30 lesthanabout50nm,lesthanabout60nm,lesthanabout ingsaredepositedontheionexchangematerialinan 70nm,lesthanabout80nm,lesthanabout90nm,les arrangementsuchasconcentric,patchwork,orcombinations thanabout10nm,lesthanabout1,0nm,lesthanabout thereof. IonExchangeMaterialofCoatedIonExchangeParticlesin nm,morethanabout20nm,morethanabout30nm,more PorousStructure 35 thanabout40nm,morethanabout50nm,morethanabout Insomeembodiments,theionexchangematerialissuit 60nm,morethanabout70nm,morethanabout80nm, ableforhighlithiumabsorptioncapacityandforlithium morethanabout90nm,morethanabout10nm,morethan ionsinaliquidresourcerelativetootherionssuchassodium about1,0nm,morethanabout10,0nm,fromabout1 ionsandmagnesiumions.Insomeembodiments,theion nmtoabout10,0nm,fromabout1nmtoabout1,0nm, exchangematerialissuitableforstronglithium ionuptakein 40 fromabout1nm toabout10nm,from about1nm toabout liquidresourcesincludingthosewithlowconcentrationsof 80nm,fromabout1nmtoabout60nm,fromabout1nm lithiumions,facileelutionoflithiumionswithasmall toabout40nm,orfromabout1nmtoabout20nm.Insome excessofacid,andfastionicdifusion. embodiments,thecoatedionexchangeparticleshavean Insomeembodiments,theionexchangematerialcom averagesizeoflesthanabout10nm,lesthanabout1,0 prisesanoxide,aphosphate,anoxyfluoride,afluorophos-45nm,orlesthanabout10,0nm.Insomeembodiments,the phate,orcombinationsthereof.Inafurtherembodiment,the coatedionexchangeparticlesaresecondaryparticlescom ionexchangematerialcomprisesLiFePO4,LiMnPOA, prisedofsmalerprimaryparticles,whereinthesecondary LiMOZ(M=Ti,Mn,Sn),LiMn3012,LiTi3012,LiMn04, particleshaveanaveragediameteroflesthanabout10nm, LiMn04,LiMO,(M=A1,Cu,Ti),LiTi04,Li,Ti,024, lesthanabout20nm,lesthanabout30nm,lesthanabout LiZVO4, LiSiz07, Li,Cup207, Al(OH)3, LiCl.xAl5040nm,lesthanabout50nm,lesthanabout60nm,les (OH)3.yH20,SnO2.xSb205.yH20,TiO2.xSb2O5.yH20, thanabout70nm,lesthanabout80nm,lesthanabout90 solidsolutionsthereof,orcombinationsthereof.Insome nm,lesthanabout10nm,lesthanabout1,0nm,les embodiment,xisselectedfrom0.1,0.2,0.3,0.4,0.5,0.6, thanabout10,0nm,lesthanabout10,0nm,more 0.7,0.8,0.9,1,2,3,4,5,6,7,8,9,and10.Insome thanabout10nm,morethanabout20nm,morethanabout embodiments,yisselectedfrom0.1,0.2,0.3,0.4,0.5,0.6,530nm,morethanabout40nm,morethanabout50nm, 0.7,0.8,0.9,1,2,3,4,5,6,7,8,9,and10.Insome morethanabout60nm,morethanabout70nm,morethan embodiments,xandyisindependentlyselectedfrom0.1, about80nm,morethanabout90nm,morethanabout10 0.2,0.3,0.4,0.5,0.6,0.7,0.8,0.9,1,2,3,4,5,6,7,8,9, nm,morethanabout1,0nm,morethanabout10,0nm, and10.Insomeembodiments,anionexchangematerial fromabout1nmtoabout10,0nm,fromabout1nmto comprises LiFePO4, LiSn03, LizMnO3, LiTiO3,60about1,0nm,fromabout1nmtoabout10nm,from LiTi,012 LiMn,012,L116Mn60%,solidsolutions about1nmtoabout80nm,fromabout1nmtoabout60nm, thereof,orcombinationsthereof. from about1nm toabout40nm,orfrom about1nm to Insomeembodiments,theionexchangematerialissyn about20nm. thesizedbyamethodsuchashydrothermal,solvothermal, Insomeembodiments,thecoatedionexchangeparticle sol-gel,solidstate,moltensaltflux,ionexchange,micro-65hasanaveragediameteroflesthanabout10um,lesthan wave,balmiling,chemicalprecipitation,co-precipitation, about20um,lesthanabout30um,lesthanabout40um, vapordeposition,orcombinationsthereof.Insomeembodi lesthanabout50um,lesthanabout60um,lesthanabout 10,0nm,lesthanabout10,0nm,morethanabout10

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