Lithium Harvesting using Membranes

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Membranes 2022, 12, 373 23 of 29 References Author Contributions: The original draft write-up for the manuscript, figures and tables were contributed equally by F.S.B., A.L. and T.C. Formatting and editing were contributed by Y.H., N.A.M. and X.W. Proof reading and editing were contributed by Y.H., J.H. (Jasmeen Hayer) and S.C. after manuscript completion. Conceptualization of the manuscript was provided by J.H. (Jilong Han), Y.Y., S.Y. and Y.H. All authors have read and agreed to the published version of the manuscript. Funding: This work was funded by [Jianshu Dingying New Materials Co., Ltd.] under Grant Number [C-00005685] and [Qinghai Haixi science and technology bureau] under [Enterprise innovation fund program number 2019-104]. Institutional Review Board Statement: Not Applicable. Acknowledgments: F.S.B. thanks the Higher Education Commission of Pakistan for awarding a PhD scholarship. A.L. acknowledges the School of Engineering for the PhD Scholarships. T.C. acknowledges The University of Edinburgh for the Principal’s Career Development PhD Scholarship and the School of Engineering for the Edinburgh Global Research Scholarship. Conflicts of Interest: The authors declare no conflict of interest. 1. Bernard, A. Lithium, Handbook on the Toxicology of Metals, 4th ed.; Elsevier: San Diego, CA, USA, 2015; Volume 1, pp. 969–974. 2. Meshram, P.; Pandey, B.D.; Mankhand, T.R. Extraction of lithium from primary and secondary sources by pre-treatment, leaching and separation: A comprehensive review. Hydrometallurgy 2014, 150, 192–208. [CrossRef] 3. Vikström, H.; Davidsson, S.; Höök, M. Lithium availability and future production outlooks. Appl. Energy 2013, 110, 252–266. [CrossRef] 4. Kesler, S.E.; Gruber, P.W.; Medina, P.A.; Keoleian, G.A.; Everson, M.P.; Wallington, T.J. Global lithium resources: Relative importance of pegmatite, brine and other deposits. Ore Geol. Rev. 2012, 48, 55–69. [CrossRef] 5. Peiró, L.T.; Méndez, G.V.; Ayres, R.U. Lithium: Sources, Production, Uses, and Recovery Outlook. JOM 2013, 65, 986–996. [CrossRef] 6. An, J.W.; Kang, D.J.; Tran, K.T.; Kim, M.J.; Lim, T.; Tran, T. Recovery of Lithium from Geothermal Brine with Lithium-Aluminum 2-Layered Double Hydroxide Chloride Sorbents. Hydrometallurgy 2012, 117–118, 64–70. [CrossRef] 7. Zhang, W.; Miao, M.; Pan, J.; Sotto, A.; Shen, J.; Gao, C.; van der Bruggen, B. Separation of divalent ions from seawater concentrate to enhance the purity of coarse salt by electrodialysis with monovalent-selective membranes. Desalination 2017, 411, 28–37. [CrossRef] 8. Ebensperger, A.; Maxwell, P.; Moscoso, C. The lithium industry: Its recent evolution and future prospects. Resour. Policy 2005, 30, 218–231. [CrossRef] 9. Kavanagh, L.; Keohane, J.; Cabellos, G.G.; Lloyd, A.; Cleary, J. Global Lithium Sources—Industrial Use and Future in the Electric Vehicle Industry: A Review. Resources 2018, 7, 57. [CrossRef] 10. Martin, G.; Rentsch, L.; Höck, M.; Bertau, M. Lithium market research—Global supply, future demand and price development. Energy Storage Mater. 2017, 6, 171–179. [CrossRef] 11. Grosjean, C.; Miranda, P.H.; Perrin, M.; Poggi, P. Assessment of world lithium resources and consequences of their geographic distribution on the expected development of the electric vehicle industry. Renew. Sustain. Energy Rev. 2012, 16, 1735–1744. [CrossRef] 12. Shi, W.; Liu, X.; Ye, C.; Cao, X.; Gao, C.; Shen, J. Efficient lithium extraction by membrane capacitive deionization incorporated with monovalent selective cation exchange membrane. Sep. Purif. Technol. 2019, 210, 885–890. [CrossRef] 13. Liu, J.; Xu, C.; Chen, Z.; Ni, S.; Shen, Z.X. Progress in aqueous rechargeable batteries. Green Energy Environ. 2018, 3, 20–41. [CrossRef] 14. Kushnir, D.; Sandén, B.A. The time dimension and lithium resource constraints for electric vehicles. Resour. Policy 2012, 37, 93–103. [CrossRef] 15. Speirs, J.; Contestabile, M.; Houari, Y.; Gross, R. The future of lithium availability for electric vehicle batteries. Renew. Sustain. Energy Rev. 2014, 35, 183–193. [CrossRef] 16. Kurzweil, P.; Brandt, K. Encyclopedia of Electrochemical Power Sources, 1st ed.; Elsevier: Amsterdam, The Netherlands, 2009; pp. 1–26. 17. Fan, Y.; Chen, X.; Legut, D.; Zhang, Q. Modeling and theoretical design of next-generation lithium metal batteries. Energy Storage Mater. 2019, 16, 169–193. [CrossRef] 18. Opitz, A.; Badami, P.; Shen, L.; Vignarooban, K.; Kannan, A.M. Can Li-Ion batteries be the panacea for automotive applications? Renew. Sustain. Energy Rev. 2017, 68, 685–692. [CrossRef] 19. Evans, A.; Strezov, V.; Evans, T.J. Assessment of utility energy storage options for increased renewable energy penetration. Renew. Sustain. Energy Rev. 2012, 16, 4141–4147. [CrossRef] 20. Flexer, V.; Baspineiro, C.F.; Galli, C.I. Lithium recovery from brines: A vital raw material for green energies with a potential environmental impact in its mining and processing. Sci. Total Environ. 2018, 639, 1188–1204. [CrossRef]

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In addition, there are many opportunities to extract Lithium from brine (salt lakes, groundwater, and producer water).

Salt water or brine are huge sources for lithium. Most of the worlds lithium is acquired from a brine source. It's even in seawater in a low concentration. Brine is also a byproduct of huge powerplants, which can now use that as an electrolyte and a huge flow battery (which allows storage at the source).

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