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Electro-Driven Materials and Processes for Lithium

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Electro-Driven Materials and Processes for Lithium ( electro-driven-materials-and-processes-lithium )

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Membranes 2022, 12, 343 21 of 27 up to 99.7% less total dissolved solids than the processed brine, in marked contrast with current practice [118]. 3.3.7. Membrane with Incorporated Metal–Organic Frameworks (MOF-on-MOF) The distinguished research was conducted on adapting the biological ion channels features to the alkali metal ions recovery (Na+, K+, and Li+). The main concept was the fab- rication of monovalent ion-selective membranes with asymmetrical sub-nanometer pores dedicated to transportation lithium cations. The ionic current measurements exhibit an un- precedented ionic current rectification ratio of above 100 with exceptionally high selectivity ratios of 84 and 80 for K+/Li+ and Na+/ Li+, respectively (1.14 Li+ mol m−2 h−1) [119]. 3.3.8. Pervaporation The modified by incorporating graphene oxide (GO) into polypropylene hollow fiber membranes (Accurel PP S6/2, from Membrana GmbH, Germany). With a high initial feed concentration (>200 g/L of salt) the GO composite pervaporation membrane increased lithium concentration from 0.3 to 1.27 g/L (73% feed volume reduction) [120]. 4. Economical Aspects of Lithium Recovery with Electro-Driven Membrane Processes Techno-economic analysis of lithium production based on three main sources of lithium: Namely, minerals, brines, and e-waste, is also discussed in the following sec- tions. Relationships between the operating conditions and the required performance are developed to shed light on the energy requirements for each source of lithium ions and the results for traditional hydrometallurgical technologies and electro-driven membrane processes or hybrid solutions are compared. 4.1. Lithium Recovery from Minerals Traditionally, for the extraction of lithium salt to produce lithium carbonate from minerals the leaching acid, alkaline, chlorination, and a combination of these techniques Membranes 2022, 11, x FOR PEER REVIEW 20 of 27 are applied. The cost factors include mine and concentrator development and construction. The distribution of cost among the individual components is shown in Figure 6a. FigFuigreur6e.6T.Thheeddisisttrriibutionoffsshhaareressofotfhtehiendinivdiidvuidalucaolmcpoomnpenotnsefnortslifthoirulmithrieucomverreycofrvoemrymfirnoemralmsinerals (a) and brines (b). [121]. (a) and brines (b) [121]. The pie chart shows that 45% of lithium recovery costs are related to the lithium car- The pie chart shows that 45% of lithium recovery costs are related to the lithium bonate plate cost. The second most expensive component is the mine and concentrator. carbonate plate cost. The second most expensive component is the mine and concentra- The dominating costs within the lithium carbonate plant are reagents, labor, and energy tor. The dominating costs within the lithium carbonate plant are reagents, labor, and costs [121]. energy costs [121]. 4.2. Lithium Recovery from Brines 4.2. Lithium Recovery from Brines For lithium recovery from brines, the evaporation methods were chosen as the main For lithium recovery from brines, the evaporation methods were chosen as the main technology at the industrial scale. Within this technique, the evaporation ponds costs play technology at the industrial scale. Within this technique, the evaporation ponds costs play an important role. The second place takes lithium carbonate plate with its utilities and infrastructure (Figure 6b) [121]. From the operational cost, the reagents’ costs seem to be the most important part. Among them, sodium carbonate (28%), calcium oxide (12%), sodium hydroxide (7%), car- bon dioxide (4%), and hydrochloric acid (1%) should be mentioned [121]. 4.3. Lithium Recovery from e-Waste Brines

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