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Electro-Driven Materials and Processes for Lithium

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Electro-Driven Materials and Processes for Lithium ( electro-driven-materials-and-processes-lithium )

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Membranes 2022, 12, 343 13 of 27 Ref. [79] [80] [80] [8] [4] [81] [82] [83] [84] Table 7. Electrodialysis process for lithium separation from aqueous solutions. Method Electrical Mode CC = 5.9 A/m2 CV = 6.0 V CV = 12–28 V CV=5V CV = 3–8 V Lithium Resources CLi+ = 0.15 g/L CMg2+ = 22.5 g/L Mg2+/Li+ CLi+ = 0.15 g/L CMg2+ = 22.5 g/L Mg2+/Li+ = 150 CLi+ = 4.5 g/L CMg2+ = 85 g/L Mg2+/Li+ = 18.9 CLi+ = 1 g/L C + = 1–30 g/L Na CCa2+ = 1–30 g/L CMg2+ = 1–30 g/L Mg2+/Li+ = 20 Membrane Type Selemion CSO Selemion ASA Selemion CSO Selemion ASA Selemion CSO Selemion ASA Neosepta CIMS Neosepta ACS n.s. AR204SXR412 and CR67, MK111 (Ionics, MA, USA) Neosepta CIMS Neosepta ACS Selemion CSO Selemion CMV Li ionic superconductor-type crystals such as Li1+x+yAlx (Ti, Ge)2−xSiyP3−yO12, (Lix, Lay) TiOz and (Lix, Lay) ZrOz can be used as LISMs Perm-Selectivity SLi/Mg = 20.2–33.0 SLi/Mg = 17.9 SLi/Mg = 9.89 Li Ions Extraction Efficiency >90% 96.1 90.5 80 60 20 75.44 63 7 Energy Efficiency 1.9 Wh/gLi+ 0.78 Wh/gLi+ 4.5 Wh/gLi+ 4.7Wh/g + Li 62 Wh/gLi+ n.s. 28.16 Wh/g + Li n.s. n.s. Advantage High selectivity for lithium ions, eco-friendly Application model real brines from East-Taijiner Microcosmic theoryof separation lithium Effect of coexisting cations on lithium separation Separation lithium toward sodium ions Separation lithium and Magnesium Separation lithium from seawater Separation lithium from model mixture of Na, ka, Mg, and Ca Limitation S Li/Mg =20 Non-equal mass balance Different perm-selectivity dependsontheinitial ratio lithium to other cations High energy consumption Low efficiency of lithium recovery High ratio of Magnesium in product Low ratio of recovery Low ratio of recovery Electrodialysis for brines SLi/Mg = 3.5–4.2 n.s. CV =7 V CLi + = 12–15 g/L CV =5 V CV = 2–3 V CV = 2 V CLi+ = 0.14 g/L CNa+ = 8.4 g/L CMg2+ = 3.04 g/L CCl- = 30.25 g/L CLi+ = 0.17 μg/L CNa+ = 105 μg/L CMg2+ = 13.5 μg/L CK+ = 3.8 μg/L n.s. S Li/Mg = 13 n.s. n.s.

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