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Minerals 2020, 10, 284 20 of 34 Minerals 2020, 10, x FOR PEER REVIEW 20 of 34 (Figure 8C). Because some wells sampled at different times are on different paths, it is not clear that 8C). Because some wells sampled at different times are on different paths, it is not clear that this this variation is real, and it may be caused by analytical error (data in [12,13]). This is supported by the variation is real, and it may be caused by analytical error (data in [12,13]). This is supported by the fact that the alluvial fan water shows a single trend. Magnesium and Ca correlate relatively well in the fact that the alluvial fan water shows a single trend. Magnesium and Ca correlate relatively well in brines (Figure 8D), but alluvial fan water does not show any correlation. This may indicate variable the brines (Figure 8D), but alluvial fan water does not show any correlation. This may indicate weathering sources of Mg. variable weathering sources of Mg. FigFiugruer8e.8C.hCehmemicaiclarlelraetliaotinosnbsebtwetweeenen(A()As)trsotnrotniutimumanadncdalcailucmiu,m(B, )(Bso)dsioudmiumandancdalciaulcmiu,m(C,)(pCo)tassium potassium and sodium, and (D) magnesium and calcium. Insets show lower concentration data in and sodium, and (D) magnesium and calcium. Insets show lower concentration data in alluvial fan alluvial fan and basin margin wells (note change in concentration units). Many alluvial fan wells do and basin margin wells (note change in concentration units). Many alluvial fan wells do not have trace not have trace element data. element data. Trace element concentrations also tend to correlate well. Lithium and Sr are highly correlated Trace element concentrations also tend to correlate well. Lithium and Sr are highly correlated with with every major cation in BDL and CDL (Figure 9A–D) except Na, which has been lost to solution every major cation in BDL and CDL (Figure 9A–D) except Na, which has been lost to solution by halite by halite precipitation at BDL. Brines on the edge of BDL and some CDL fluids that are below halite precipitation at BDL. Brines on the edge of BDL and some CDL fluids that are below halite saturation saturation do show a correlation between Na and Li, but there are not enough data in DDL to do show a correlation between Na and Li, but there are not enough data in DDL to determine whether determine whether major cations correlate with lithium. major cations correlate with lithium. BDL brines overall are slightly more saline than CDL brines but have also precipitated far more halite than CDL [26], indicating that BDL is more evaporated and evolved than the CDL brine. Boron and F are not correlated in any of the brines (data in [12,13]); Figure 10) and concentrations in the basin-center brines are not much higher than in the alluvial fan water. This suggests that both elements are adsorbed to/precipitate with clay minerals as they get to the playa center.PDF Image | Bristol Dry Lake Brine Compared to Brines from Cadiz
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