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ElelcetrcontircoTrnanicspoTrtrParonpesrtpieosorftFPewr-oLapyeerGrtriaephsenoefMaFteriawls-LayerGrapheneMaterials 147 the stability of these 4 Dirac cones against electron-electron interactions and/or mechanical deformations are at the focus of both theoretical and experimental research. ABA 00 ABC γ3 γ4 γ2 γ4 γ A1 B1 γ A1 B1 γ1 A2 B2 γ1 γ A2 γ3 γ4 γ2 5 B2 B3 A3 b) A3 B3 a) γ3 γ4 γ3 Fig. 4. Panels (a) and (b) show respectively the crystal structure of Bernal stacked and rhombohedral stacked trilayer graphene with the complete set of tight binding parameters. For multilayers of more than two layers, there are two known structures called respectively ABA (hexagonal or Bernal) and ABC (rhombohedral) with different stacking manners as shown in Fig. 4a and b. For ABA multilayer graphene, the Hamiltonian can be approximately decomposed into a superposition of the monolayer-like and bilayer-like subsystems (Koshino et al. (2007; 2008); Partoens et al. (2006; 2007)). Specifically, 2M-layer graphene contains M bilayer-like subbands, while (2M + 1)-layer graphene has M bilayer-like subbands and one monolayer-like subband. The subbands appearing in N-layer graphene are characterized by a single parameter (Guinea et al. (2006); Koshino et al. (2007; 2008)): λ=2cos nπ , (12) N+1 where n = 1, 2, · · · , [(N + 1)/2] is the subband index and [(N + 1)/2] is the maximum integer which does not exceed (N + 1)/2. The sub-Hamiltonian of λ ̸= 0 is equivalent to that of bilayer graphene with the nearest interlayer coupling parameters multiplied by λ, while that of λ = 0, appearing in odd N only, becomes that of monolayer graphene. For instance, the trilayer-graphene comprises six bands of which two have linear (monolayer-like) dispersion and four have parabolic dispersion (bilayer-like). On the other hand, ABC multilayers have quite different electronic structures: the low-energy spectrum contains only a pair of conduction and valence bands touching at zero energy (Avetisyan et al. (2010); Guinea et al. (2006); Koshino et al. (2009); Koshino (2010); Min et al. (2008)). These two bands are given by the surface states localized at outer-most layers, and the dispersion is roughly proportional to kN , and becomes flatter as N increases.PDF Image | GRAPHENE SYNTHESIS CHARACTERIZATION PROPERTIES
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