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and might alleviate some of the issues still associated with deep-cycling Li/S cells. As prices go down – and potentially, the price of Li/S batteries could be very low [32, 33] – this technology also becomes more attractive for large-scale grid storage ap- plications [9]. Already today, the electrochemical storage and controlled use of wind and solar energy is more cost-effective than immediately feeding all power into the electricity grid as it becomes available [294, 295]. Still, the segment of grid storage is dominated by pumped hydro-power. Other technologies such as high-temperature Na/S batteries or flywheels are used for special purposes only, e.g. short term high- power supply [9]. The further advancement of Li/S batteries, but also other tech- nologies, e.g. novel flow batteries [296, 297], or improved fuel cells and electrolyzers [298–300], might fundamentally change the game. To conclude, more research is needed in order to advance the understanding, opti- mization, and application of batteries in general and Li/S technology in particular. In this regard, it is a good sign that policy makers seem to realize that the development of next-generation systems for electrical energy storage is one of the high importance, high impact research topics of the next decade(s). Consequently, there is an increasing number of publicly and privately funded efforts worldwide [54]. These include the activities of the Helmholtz Society, the German Aerospace Center, and the Helmholtz Institute Ulm, promoting this dissertation. 142PDF Image | Lithium-Sulfur Battery: Design, Characterization, and Physically-based Modeling
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