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364 Handbook on the Physics and Chemistry of Rare Earths FIG. 7 Spatiotemporal resolution of noncontact thermometers. Adapted with permission from Brites, C.D.S., Lima, P.P., Silva, N.J.O., Milla ́n, A., Amaral, V.S., Palacio, F., Carlos, L.D. 2013a. Organic–inorganic Eu3+/Tb3+ codoped hybrid films for temperature mapping in integrated circuits. Front. Chem. 1, 9. the device (Sa ̈ıdi et al., 2011). In Section 5, we will discuss some examples of Yb3+/Er3+-doped UCNPs. Very recently, the use of negatively charged nitrogen vacancy for SThM was reported by Tetienne et al. (2016). The spin of the nitrogen vacancy can be used as a sensitive thermometer by relying on the temperature depen- dence of the crystal field splitting parameter. The authors mapped the temper- ature of a plasmonic heated gold NP with a temperature uncertainty dT 1⁄4 30 K and a spatial resolution of 0.1 mm. The temporal resolution of the measure- ment is defined by the pixel integration time (1.5 s) preventing the monitoring of the photodynamic heating process (Tetienne et al., 2016). Sedmak et al. incorporated in the scanning probe a Yb3+/Er3+ transparent glass ceramic and a GFP (Sedmak et al., 2015). The transient heat-conduction experiments were performed in the 273–423 K range. A spatial resolution of 400 nm was achieved across an approximately 200 200 mm2 field of view at an imaging frequency of 7 Hz, corresponding to a temporal resolution of dt 1⁄4 0.14 s (Sedmak et al., 2015).PDF Image | HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS
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