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11. Wang H, et al. Tailored Reaction Route by Micropore Confinement for Li–S Batteries Operating under Lean Electrolyte Conditions. Adv Energy Mater 8, 1800590 (2018). 12. Shen C, et al. Understanding the role of lithium polysulfide solubility in limiting lithium- sulfur cell capacity. Electrochim Acta 248, 90-97 (2017). 13. Li W, et al. The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth. Nat Commun 6, 7436 (2015). 14. Dokko K, et al. Solvate Ionic Liquid Electrolyte for Li–S Batteries. J Electrochem Soc 160, A1304-A1310 (2013). 15. Wang Q, et al. Direct Observation of Sulfur Radicals as Reaction Media in Lithium Sulfur Batteries. J Electrochem Soc 162, A474-A478 (2015). 16. Aurbach D, Pollak E, Elazari R, Salitra G, Kelley CS, Affinito J. On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries. J Electrochem Soc 156, A694-A702 (2009). 17. Xiong S, Xie K, Diao Y, Hong X. Characterization of the solid electrolyte interphase on lithium anode for preventing the shuttle mechanism in lithium-sulfur batteries. J Power Sources 246, 840-845 (2014). 18. Barchasz C, Molton F, Duboc C, Leprêtre J-C, Patoux S, Alloin F. Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification. Anal Chem 84, 3973-3980 (2012). 19.Ren YX, Zhao TS, Liu M, Tan P, Zeng YK. Modeling of lithium-sulfur batteries incorporating the effect of Li2S precipitation. J Power Sources 336, 115-125 (2016). 20. Cuisinier M, Cabelguen PE, Adams BD, Garsuch A, Balasubramanian M, Nazar LF. Unique behaviour of nonsolvents for polysulphides in lithium–sulphur batteries. Energy Environ Sci 7, 2697-2705 (2014). 21. Lee C-W, et al. Directing the Lithium–Sulfur Reaction Pathway via Sparingly Solvating Electrolytes for High Energy Density Batteries. ACS Cent Sci 3, 605-613 (2017). Page 21 of 24PDF Image | A lithium-sulfur battery with a solution-mediated pathway
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