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Theory of shock electrodialysis

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Theory of shock electrodialysis ( theory-shock-electrodialysis )

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(a) пмппт anode,ܙ = щ/2 Ѣ и , ѐ ји Inlet Ѣ і ћ , ѐ јі Ѧ Ѣ и , ѐ ји ќѥ (b) ѧ ќѥ (c) ѧ ќѥ non-penetrating walls CEM charged channel (-) м outlet Ѣ е , ѐ је outlet Ѣ й , ѐ јй CEM cathode, ܙ = Ȓ щ / 2 charged channel (-) Figure 2: Two systems (a single channel and a stack) used in this paper to model shock ED. (a) Projection of both systems in the xy-plane, (b) projection of the single-channel in the xz-plane, and (c) projection of the stack in xz-plane. conditions when dealing with multiple ions. Lastly, this model system also includes the unsupported elec- trolyte (i.e., a matrix with no charge) at the inlet and outlet, which can capture the streaming potential as well as regulate the flow and transport in the charged channel. 2. Depth-averaged model for planar shock ED system In this section, we will provide a depth-averaged model for multiple ion transport in the single-channel system shown in Fig.2(a)(b). The system mimics the shock ED prototype in Fig.2, but it uses a planar, charged channel instead of the macroporous material. Two uncharged microchannels (one as the inlet and the other as the outlet) are connected to the charged channel, which allows us to use pore-scale equations to describe the transport in the feed stream, as presented in Sec.2.1. We will then simplify the model under the assumption of thin channels in Sec.2.2, derive the depth-averaged equations in Sec.2.3, and give the boundary conditions of the feed channel in Sec.2.4. Finally we will nondimensionalize the model in Sec.2.5 and extend the model for a stack of charged channels (Fig.2(c)) in Sec.2.6. 2.1. General equations Shock ED is a nonlinear process, where the ion concentration for each species c1, c2, ···cN, the flow velocity u = {u, v, w}, the electric potential ψ, and the hydraulic pressure p are coupled. Here N = Ns + 2 is the total number of species, and we denote salt ions by subscripts k = 1,2,··· ,Ns, H+ by k = Ns + 1, and OH− by k = Ns + 2. There are N + 5 variables in total for a three-dimensional system, and we need the same number of equations to solve for them. To begin with, ions are transported by convection, diffusion, and electromigration. For species k (k = 1, 2, · · · , N unless specified otherwise) in a dilute solution, ion flux Jk can be described by the Nernst-Plank equation Jk =uck−Dk􏱐∇ck+zkck∇ψ􏱑, (1) VT where Dk, zk are respectively the diffusivity and valence of the species k, VT = kbT/e is the thermal voltage where kb is the Boltzmann constant, T is the temperature, and e is the electron charge. We can add the ion 3 2Ďу 2Ďу 2Ďіќ 2Ďіќ ли ліќ лѠліќ ли ліќ лй ле л лр

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