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SUPERCRITICALCARBON DIOXIDE DRY CLEANING SYSTEM

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SUPERCRITICALCARBON DIOXIDE DRY CLEANING SYSTEM ( supercriticalcarbon-dioxide-dry-cleaning-system )

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UnitedStatesPatent [19] Deweesetal. [54] LIQUID/SUPERCRITICALCARBON DIOXIDE DRY CLEANING SYSTEM [75] Inventors: ThomasG.Dewees,Pleasanton; Frank M. Knafelc, Lafayette; James D. Mitchell, Alamo; R. Gregory Taylor,Pleasanton;RobertJ.Ilif, Oakley;DanielT.Carty,Danville; James R. Latham, Livermore; Thomas M. Lipton, Concord, alof Calif. [73] Assignee: TheCloroxCompany,Oakland,Calif. [21] Appl.No.: 912,932 [2] Filed: Jul.13,1992 [51] Int.Cl.5 ..D06F 43/02; D06F 43/08 [52] US. Cl. .. 68/5 C; 34/72; 68/18 R; 68/18 C; 68/18 F [58] Field of Search ..68/5 C, 18 R, 18 C, lIlilIlil US005267455A [1] PatentNumber: 5,267,455 [45] DateofPatent: Dec.7,1993 Chemical Technology. 3d edition, (1978), Supplement Volume, pp. 875-893. “CarbonDioxide,"Kirk-OthmerEncyclopediaofChem icaI Technology, 3d edition (1978), vol. 4, pp. 725-742. Francis, Alfred W., “Ternary Systems of Liquid Car bon Dioxide,” vol. 58, (Dec. 1954), pp. 1099-1114. Poulakis et al., “Dyeing Polyester in Supercritical CO2,” Chemiefasern/Textilindustrie, vol. 41/93 (Feb. 1991), pp. 142-147. Cygnarowiczetal.,“EffectofRetrogradeSolubilityon the Design Optimization of Supercritical Extraction Processes,” 1&EC Research, vol. 28, No. 10 (1989), pp. 1497-1503. ' Motyl, Keith M., “Cleaning Metal Substrates Using Liquid/Supercritical Fluid Carbon Dioxide,” Report by Rockwell International for US. Department of En ergy, REP-4150 (Jan. 1988), pp. 1-29 (odd pages). Hyatt, John A., “Liquid and Supercritical Carbon Di— oxide as Organic Solvents,” J. Org. Chem, vol. 49, No. 26 (1984), pp. 5097-5100. Brogle, Heidi, “CO2 as a Solvent: Its Properties and Applications,” Chemistry and Industry, (Jun. 19, 1982), pp. 385-390. PrimaryExaminer-PhilipR.Coe Attorney,Agent,orFirm-Majestic,Parsons,Siebert& Hsue [57] ABSTRACT A drycleaningsystemparticularlysuitedforemploying Supercritical CO2 as the cleaning fluid consisting of a scalable cleaning vessel containing a rotatable drum adapted for holding soiled substrate, a cleaning ?uid storage vessel, and a gas vaporizer vessel for recycling used cleaning fluid is provided. The drum is magneti cally coupled to a motor so that itan be rotated during the cleaning process. The system isadapted for automa tion which permits increased energy ef?ciency as the heating and cooling effect associated with CO2 gas condensation and expansion can be channeled to heat and cool various parts of the system. 10 Claims, 3 Drawing Sheets 23 [56] 68/18 F; 134/951; 34/26, 32, 36, 72, 74 References Cited U.S. PATENT DOCUMENTS 3,969,196 7/1976 Zosel . 4,012,194 3/1977 Maffei . 4,219,333 8/1980 Harris . 5,013,366 5/1991 Jacksoneta1.. 5,123,176 6/1992 Yamadaeta1...34/32 FOREIGN PATENT DOCUMENTS 0518653Al 12/1992 European Pat. Off. . 0530949Al 3/1993 European Pat. Off. . 2027003 6/1970 Fed. Rep. ofGermany . 3906735 6/1990 Fed. Rep. of Germany . 3904513 8/1990 Fed. Rep. ofGermany . 3904514 8/1990 Fed.Rep.ofGermany . 4004111 15/1990 Fed.Rep.ofGermany . 3906724 9/1990 Fed. Rep. ofGermany . 90/06189 6/1990 PCT lnt’lAppl. . OTHER PUBLICATIONS Motyl, Keith M., “Cleaning Metal Substrates Using Liquid/Supercritical Fluid Carbon Dioxide,” NASA Tech Briefs MFS-296ll (undated). “Supercritical Fluids,” Kirk-Othmer Encyclopedia of

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