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D APPENDIX D: TECHNOLOGY SOLUTIONS FOR ENERGY RECOVERY Figure D.7: Relative emissive power as a function of wavelength with Ni-doped MgO and Er-YAG emitter effective regions. Note the energy conversion limit for GaSb and GaInSb photovoltaics are at approximately 1.8 μm. Charge Transfer and Bandgap Theory Multiple theories have been advanced to explain interactions between matter and radiation and the resulting spectral behavior. Ionic models, energy band models, crystal field and ligand field theories, and molecular orbital theory are but a few. No single theory adequately describes the entire radiation spectrum of transition-metal doped selective emitters. Figure D.8 is a qualitative diagram of the high-temperature emittance of a selective ceramic oxide emitter with a small percentage (~1 at %) of Co or Ni transition-metal impurities. Each component of the spectrum is identified with a dominant underlying radiation mechanism. 110PDF Image | Analysis for Recovering Energy from Industrial Waste Heat
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