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Chapter 2 Summarizing, the selection of the working fluid affects at the same time the thermodynamic performance of the system, and the design of all its components. For a detailed treatment, the reader is referred to Ref. [7]. For example, if the thermal energy source features a relatively small potential and a rather high- temperature (say 2 MWT, and Tsource > 300 oC), the selection of a fluid formed by complex molecules (large specific heat) yields to a slightly superheated and regenerated cycle as the corresponding optimal cycle configuration. The rela- tively large volume flow due to the small enthalpy drop over the expansion allows for the design of an efficient and simple turbine, with sufficiently large flow pas- sages. In particular, the small specific expansion work allows also to limit the number of stages (e.g., 2 or 3), and the resulting rotational speed may be 10 − 20 times smaller compared to a steam turbine for the same operating conditions. The dominant need of reducing the number of stages, this increasing their pressure ratios, together with the low values of the sound speed of the expanding organic vapor, leads in most cases to the acceptance of highly supersonic flows, at least in the first stator, which therefore requires special care in the fluid dynamic de- sign. Depending on the condensing temperature, the volume flow at the outlet of the turbine can be large, thus requiring a comparatively bulky regenerator and condenser. As a consequence, cost issues related to the heat transfer equipment might arise. Additional challenges ensue in case vacuum conditions have to be managed. Conversely, the overall low maximum pressures in the system can be beneficial as far as the cost of the evaporator and safety issues are concerned. It is also notable that regeneration positively affects the thermal efficiency of the cy- cle, but negatively affects the temperature at which the heat source can be cooled (limited by the temperature of state 3 in figure 2.1a), thereby the amount of ther- mal power that can be converted into mechanical power. Similar reasoning can be applied to other applications, e.g., low- and medium-temperature geothermal energy conversion, leading to different results. The working fluid is also subjected to a number of other constraints, which can be more or less stringent depending on the application, namely the fluid should be ◦ non-toxic, non-flammable, non-corrosive, and cost-effective, ◦ characterizedbyaloworzeroGlobalWarmingPotential(GWP)andOzone Depletion Potential (ODP), ◦ thermally stable and compatible with all the containing and sealing materi- als up to the cycle maximum temperature, ◦ possibly a good lubricant, featuring also good heat transfer properties, 14PDF Image | New Concepts FOR Organic Rankine Cycle Power Systems
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