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we used to examine the microstructure of supercritical conditions with regard to local structure using the KB theory In the application of the KB theory to the systems 1. Pure carbon dioxide 2. Infinite dilution of methane in carbon dioxide 3. Infinite dilution of water in carbon dioxide We identify three types of local microstructure. Type A. There is local density enhancement of CO2 around a CO2 molecule. This density enhancement is more pronounced at densities below the critical one (ca. 2/3ρc). In other words there is a sponge like structure of CO2 molecules in supercritical region which is more evident at densities below the critical density along an isotherm. Type B. There is also a density enhancement around a water molecule in CO2 molecules. This has been identified as an excess of CO2 molecules around a water molecule. Rephrasing, the water molecule prefers to solvate in high density region of carbon dioxide. Type C. There is a density depletion of CO2 molecules around a methane molecule. In this situation, this has been identified as a deficit of CO2 molecules around a methane molecule. In other words, the water molecule prefers to solvate in areas where there is cavitation. An apparently counter-intuitive point in the three different pictures of solvation is that they follow the same trend. They show the most anomalous behaviour at the same densities along the critical isotherm. Two unrelated solutes, when being dissolved in supercritical carbon dioxide, follow somehow a ‘universal’ behaviour, despite the fact that they follow a different type of solvation. This universal behaviour is related more to the properties of the supercritical carbon dioxide rather than the properties of the individual solutes, water or methane. In other 144PDF Image | MOLECULAR SIMULATION STUDIES IN THE SUPERCRITICAL REGION
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