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Recovering Lithium Chloride From a Geothermal Brine 1984

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Recovering Lithium Chloride From a Geothermal Brine 1984 ( recovering-lithium-chloride-from-geothermal-brine-1984 )

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12 decomposed to a water-soluble hydroxy- exothermic sparging step and be used to chloride. The decomposition would pro- evaporate part of the water. An energy duce HCl, which could be recycled to balance should be combined with data from dissolution of the Li-Al precipitate. power generation test facilities. An- Water-soluble hydroxy-chloride having other benefit of combining costs for LiCI a composition of 5AlC13:8Al(OH)3:37.5HzO recovery with those for power generation has been obtained during leaching of kaolinitic clays, but it is not known whether this specie can be formed from ACH. The next largest cost factor is fuel oil for spray drying. Other drying tech- niques, such as multiple-effect evapora- tion, might decrease the cost, but a final spray drying step would be needed to eliminate pulverization of the solid mixed chlorides. Part of the heat re- quirements for evaporation may be ob- tained from steam available from a power generation plant after the steam exits the turbine. The low-grade steam could extract part of the heat from the is the water balance. Steam used to gen- erate electricity is presently condensed and returned to the injection well to maintain reservoir pressure. Since the condensed steam is potable water, mini- mizing the amount returned to injection would provide a valuable byproduct. Treatment of the spent brine at a 50-MW powerplant for lithium recovery increases the mass from 42,000 to 43,948 tpd. Of the increase, 1,721 tpd is water added with the reagents. The remaining 227 tpd is due to added reagents and the chemical reactions taking place. This 227 tpd represents 54,500 gpd of potable water, which would not need to be injected. SUMMARY AND CONCLUSIONS A lithium recovery system in which brine returning to an injection well from a power generation facility may be treat- ed to recover a lithium chloride product was devised. Each unit operation was mately equal to the present market price studied and gave at least 95-pct lithium but could be decreased by combining lith- recovery. Overall lithium recovery was ium recovery with some of the operations 89 pct. The lithium product contained used in power generation instead of 330 giL LiCl, was 99.9 pct pure, and treating it as an isolated process. REFERENCES 1. Carter, J. P., F. x. McCawley, Mineral Extraction Complex. Phase 1. S. D. Cramer, and P. B. Needham, Jr. Preliminary Technical and Economic As- Corrosion Studies in Brines of the Salton sessment (contract J0275010, DSS Engi- Sea Geothermal Field. BuMines RI 8350, neering, Inc.). BuMines OFR 51-79, 1979, 1979, 35 pp. 194 pp. 2. Cramer, S. D., and J. P. Carter. 4. Berthold, C. E., P. Hadzeriga, Laboratory Corrosion Studies .in Low- and D. H. Christopher, T. A. Applegate, and High-Salinity Geobrines of the Imperial D. M. Gillespie. Process Technology For Valley, Calif. BuMines RI 8415, 1980, Recovering Geothermal Brine Minerals 30 pp. (contract S0133084, Hazen Research, Inc.) BuMines OFR 35-75, 1975, 255 pp.; NTIS, 3. Urbanek, M. W., C. D. Hornberg, PB 241 867/AS. and B. Lindal. Research on a Geothermal could be used "as is" or dried to anhy- drous LiCI. The cost of recovering LiCI is approxi-

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