Process of Lithium Recovery from Geothermal Brine

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mbrane Per- formance Number of Number of Re- 1410 923+1 Recovered Li , 1275 8321 Spec Crystalized Outp 425 NaCl, kg g(Li+)/ ul 3289 35 107 3055 42 2886 39 3308 67 2952 80 2579 10 Membranes 2021, 11, 175 13 of 20 ratio RR, which defines the lifetime of the membrane module, rather than the run time of the module before washing Rt. The further optimization of the membrane module used can be achieved by the increase of their lifetime before replacement. As can be seen from Table 6, the drop in the membrane performance threshold MPT from 50 down to 30% for the worst-case scenario considered in this work (Rt = 4.5 h, RR of 95%) can decrease the number of replaced membrane modules from 21 down to 12 resulted in the increase of specific recovery rate from 67 up to 107 g(Li+)/module. In addition, we have also used the literature data on the concentration of nearly saturated brine solution by using a different configuration of membrane distillation for process simulation (Table 7). To our best knowl- edge, the simulation made based on the different membrane performance revealed the highest specific output was 2200 g(Li+) per module used (surface area of 2.5 m2 was fixed) for the integrated system based on the direct contact membrane distillation and multi-stage crystallization system [53] (see Table 6). In other words, the best reported in the literature configuration would allow for recovering 880 g(Li+) per 1 m2 of the membrane in the module. Taking into account the fact that the recovery of 0.9-1.4 kg of Li+ was associated with the precipitation of about 2.1–3.3 tons of NaCl in the crystallizer (see Table 5), the 14 potential loss of lithium as a result of so-crystallization shall also be considered in the further study. mbranes 2021, 11, 175 Table 6. Effect of membrane performance threshold MPT on process parameters (two months of operation). Simulation conditions: Tf = 60◦C, Rt = 4.5 h, S = 2.5 m2, CF = 20, ER(Li+) = 90%. Table 6. Effect of membrane performance threshold MPT on process parameters (two months of operation). Simu- Figure 8. Effect of run time Rt and recovery ratio RR on lithium recovery per membrane module. Figure 8. Effect of run time Rt and recovery ratio RR on lithium recovery per membran Simulationconditions:Tf =60◦C,Rt=4h,RR=99%,MPT=50%,S=2.5m2,CF=20,ER(Li+)=90%. module. Simulation conditions: Tf = 60 °C, Rt = 4 h, RR = 99%, MPT = 50%, S = 2.5 m2, C 20, ER(Li+) = 90%. Membrane Recovery Number of Number of 2+ lation Pceorfnodrmitainocens: Tf = 60°C, RtB=uil4d.-5Uph, S = 2.5 m , CF =Re2p0la,cEedR(Li R)e=co9ve0r%ed. Evaporated Water, kg Crystalized NaCl, kg 3055 Specific Output, g(Li+)/Module Threshold MPT, % Ratio RR, % Time, Hours Membrane Washing Membrane Li+, kg Modules Threshold MPT, % 50 40 30 50 40 30 RR, % Time, Hours 1176 1410 1274 1287 kg 1410 1275 1176 1410 1274 1287 7520 9173 8296 7254 Water, kg 50 99 467 288 4 3289 353 Recovery Ratio Build-Up 40 99 528 Mem2b88rane pla3ced Mem- Evaporated 30 99 618 288 3 2886 392 Washing brane Modules 21 16 12 50 40 30 99 99 99 95 95 95 95 95 95 491 288 541 288 4 3 3 21 16 12 3308 2952 67 80 467 288 9231 612 288 2579 8321 7520 9173 8296 7254 528 288 618 288 491 288 541 288 612 288 Table 7. Comparison of different configurations and performance of MD process reported in the literature and inthis work (two months of operation). Simulation conditions: RR = 50%, S = 2.5 m2, CF = 20, ER(Li+) = 90%. e F ei M e 3 5 2 7

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In addition, there are many opportunities to extract Lithium from brine (salt lakes, groundwater, and producer water).

Salt water or brine are huge sources for lithium. Most of the worlds lithium is acquired from a brine source. It's even in seawater in a low concentration. Brine is also a byproduct of huge powerplants, which can now use that as an electrolyte and a huge flow battery (which allows storage at the source).

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