Origin of Lithium Potassium Rich Brines in the Jianghan

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Minerals 2021, 11, 1330 14 of 23 Minerals 2021, 11, 1330 15 of 24 5.2. Determination of the Starting and Stopping Temperatures of the Water–Rock Reaction The homogenization temperature range of gas–liquid two-phase inclusions in granite varies greatly, with a concentration range of 170–230 ◦C and an average homogenization temperature of 210.1 ◦C, indicating that the fluid temperature of the water–rock reaction is high, and the lowest temperature of mineralization is 210.1 ◦C [53]. Therefore, the initial temperature of the water–rock reaction in igneous rock was set at 150–200 ◦C, and the experimental temperature range was set at 150–400 ◦C to explore the effect of the water–rock reaction on brine mineralization. 5.3. Discussion on the Genesis of Lithium–Potassium-Rich Brine 5.3.1. Analysis of Static Immersion Experimental Results The contents of K in the five fluids were different, but the trend was similar. Most of the K content in the solution was the highest after soaking for 55 h after the seventh sampling. Moreover, weakly alkaline (pH = 8) solutions and 1 mol/L and 2 mol/L NaCl solutions were more conducive to K leaching (Figure 7). At room temperature, the content of K in the 2 mol/L NaCl was higher than that in the 1 mol/L NaCl solution, and the dissolution amount of K in the 1 mol/L of NaCl solution was 10.90 mg/L. However, its concentration increased with increasing salinity and soaking time. In the 2 mol/L NaCl solution, the maximum value was 14.86 mg/L. Basalt immersion was more conducive to potassium dissolution than granite, and the dissolution amount was one order of magnitude higher (Table 4). Figure 7. Variation diagram of K ion concentration in igneousrock static immersion experiment. Figure 7. Variation diagram of K ion concentration in igneousrock static immersion experiment. Caa,,Mg,,andSr showedaconssiisstteenntttrtreenndd,,wwitihthththeehihgihgehsetsetlemlemenetnctocnotenntetnint itnheth1e 1mool/lL/Lanadnd22mmolo/Ll/NLaNCalCsollsuotliountiso,nfso,llfowlloedwbedybthyetshoelustoilountiwonithwpitHhp=H5;=th5e;tlohweeloswtels-t eelemmeennttcoconntetnenttwwaassininththeeddisistitlileleddwaateterraannddththeessoolulutitoionnwitihthppH==88(F(Figiguureress88––1100),),inin whhicichhtthheecconttenttoffCawasthehighest, followedbyMg,,andthellowessttwaassSSrr..Witihth ininccrreeaassininggsosaokakininggtimtime,et,hethdeisdsoislsuotliuotnioanmaomunotuonftthoef threeethkrienedskionfdiosnosfiniocnresasinedcrselaoswedly. Astlorwoolym. Atetmropoemrattuerme,ptehreatCuar,eM, thge, aCnad, SMrgc,oanntednStsricno2ntmenotls/iLnN2amCollw/LerNeagCelnwerearlelygheingehre-r tahlalynhthigohserinth1anmtohlo/sLe iNna1Cml sool/lLutNioanC.lIsnotluhteio1nm. Ionl/thLeN1amColls/LolNutaiConl,sothluetmiona,xitmheumaCx-a diimssuomlutCioandaimssouluntiwonasa2m9o0u.4n0tmwga/sL2,9a0n.d40thmecgo/Ln,ceantdrathioencofnCceanintrcarteiaosnedofwCitahincreaseindg swalitnhitiynacrnedasiminmgesarslinointytimaned.Timhemmerasxioimnutimev.aTluheeomfCaxaiminutmhev2amluoel/oLfCNaCinlsthoelu2tiomnowl/Las 3N43a.C45lmsoglu/tLio.nInwthaes134m3o.4l5/LmNg/aLC.lIsnotluhteio1nm,tohle/LmNaxaiCmlusmoluMtigond,istshoelumtiaoxnimwuams18M.9g7dmisgs/oL-, wluhtiloeninwtahse182.9m7oml/gL/LN, waChlilseoilnuthioen2, mthoel/mLaNxaimClusmoluMtigond,isthsoelmutaioxinmwumas M22g.7d9isMsogl/utLio. nIn 1wmaosl2/2L.7N9aMCgl/sLo.luIntio1nm,othl/eLmNaxCimlsuomlutSirorne,ltehaesemwaaxsim1.u5m9mSgr/reLl,ewasheilweainst1h.5e92mgo/lL/,LwNhailCel sionluthtieon2 ,mthoel/mL aNxaimClusmoluStriorenl,etahse mwaxsim1.9u0mmSgr/rLele(Taaseblwe a4s).1.90 mg/L (Table 4). No concentration of lithium was detected in the five fluids. Br, I, and B were not detected in distilled water, pH = 5, and pH = 8 solutions but were detected in the 1 mol/L and 2 mol/L NaCl solutions. The changes in Br, I, and B in 1 mol/L and 2 mol/L NaCl solutions are discussed as follows:

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