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Extraction of Lithium from Single-Crystalline Lithium

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Extraction of Lithium from Single-Crystalline Lithium ( extraction-lithium-from-single-crystalline-lithium )

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Table S1 Comparison of the extraction strategy developed in this work with other studies. Related to Figure 4. Materials Li1.33Mn1.67O4 Li1.33Mn1.67O4/Al2O3 Li1.33Mn1.67O4/NiO Li4Mn5O12 Li4Mn5O12 LiMn2O4 Li1.6Mn1.6O4 LiMn2O4 LiMn2O4 LiMn2O4 Li1.33Mn1.67O4 Li4Mn5O12/CTS Li2TiO3/PVC Li1.1Mn1.9O4 Synthesis method solid-phase solid-phase solid-phase solid-phase solid-phase hydrothermal solid-phase Sample Natural Brine Natural Brine Natural Brine Qarhan Brine LiCl solution LiCl solution LiCl solution Li+ concentraction (mg/L) 1458 1458 1458 179 69 69.4 83 20 20 50 30 25.78 25.78 694 Li+ T/pH uptake (mg/g) Qth Efficiency (mg/g) (%) 56 54 56 63 56 64 56 5 56 71 38 55 68 47 38 90 38 85 38 64 56 54 56 16 127 10 44 90 Manganese dissolution 1.30% 0.99% 1.15% 1.90% 1.90% N/A 4.00% N/A N/A 3.90% N/A 0.60% N/A 0.08% Reference (Ohashi and Tai, 2019) (Ohashi and Tai, 2019) (Ohashi and Tai, 2019) (Xiao et al., 2015) (Xiao et al., 2015) (Zhang et al., 2010) (Qian et al., 2020) (Özgür, 2010) (Özgür, 2010) (Yang et al., 2018) (Hong et al., 2013) (Wang et al., 2020) (Lin et al., 2019) This work Spray LiOH Pyrolysis solution solid-phase hydrothermal solid-phase solid-phase solid-phase hydrothermal LiOH solution LiCl·H2O solution Li-spiked Seawater geotherm al water geotherm al water LiCl solution 25 10 9 12.84 39 25°C/6. 5 25°C/6. 5 25°C/6. 5 25°C/6. 4 30°C/1 0.1 30°C/1 0.1 25°C/N 32 25°C/N 35 25°C/N 33 18°C/1 0.0 16°C/7 -8 30°C/1 2 55°C/1 2 60°C/8. 0 30 35 36 3 40 21 Qth is the theoretical adsorption capacity of sorbent, calculated based on its composition; whereas the efficiency is obtained using a measured Li+ uptake divided by the theoretical adsorption capacity.

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