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Bipolar Membrane Electrodialysis for LiOH Production

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Bipolar Membrane Electrodialysis for LiOH Production ( bipolar-membrane-electrodialysis-lioh-production )

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Membranes 2021, 11, x FOR PEER REVIEW 18 of 30 Membranes 2021, 11, 575 17 of 29 Figure 8. Linear sweep voltammetry of bipolar membranes under production operating conditions: (a) Fumasep FBM; Figure 8. Linear sweep voltammetry of bipolar membranes under production operating conditions: (a) Fumasep FBM; (b) (b) Neosepta BP. Neosepta BP. 3.3.3. Linear Sweep Voltammetry in Cation-Exchange Membranes. Linear sweep voltammetry was performed on the CMX and CMB membranes at dif- ferent LiOH concentrations. Figure 9 presents a comparative plot of the different current– voltage curves obtained. Current variation with potential was linear for the measurement range used, and limiting current density was not reached in any case. It can be observed from the graph that current densities close to 5000 A∙m−2 for the CMX membrane, and between 2200 and 3500 A∙m−2 for the CMB membrane, were reached for a potential range between 0 and 1.8 V. This indicates that the high electrolyte concentrations studied allow high availability of Li+ ions on the membrane surface to migrate across the membrane without the occurrence of concentration polarization. The highest current densities were reached at higher electrolyte concentrations. For theCMX membrane, the current density

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