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434 Index OP Order parameter, 298–299 Overlapped transitions, Boltzmann law Gaussian peaks, 373–375, 374f upconverting emission spectrum, 373–375, 375f Oxides green-emitting phosphors Ba2MgSi2O7:Eu2+, 31–34, 32–34f, 33t Ba9Sc2Si6O24:Eu2+, 34–35, 35–36f CaSc2O4:Ce3+, 29–31, 30–31f Ca3Sc2Si3O12:Ce3+, 28–29, 28–29f nephelauxetic effect, 15 red-emitting phosphors Ca2SiO4:Eu2+, 35–37, 37f, 37t olivine-type NaMgPO4:Eu2+, 38–39, 38–39f synthesis methods aerosol, 81 liquid phase precursors, 79–81 rapid heating process, 82 silicon monoxide (SiO), 81 solid-state reactions, 78–79 yellow-emitting phosphors Ba3Sc4O9:Ce3+, 26–28, 27f Li2SrSiO4:Eu2+, 24–25, 25–26f Sr-rich (Ba,Sr)2SiO4:Eu2+, 19–22, 20–21f Sr3SiO5:Eu2+, 22–24, 22–24f Y3Al5O12:Ce3+, 15–19, 16–19f Oxychlorides, 72–73, 73–74f Oxyfluorides Ca8Mg(SiO4)4Cl2:Eu2+ phosphors, 67–68, 68–69f (Ca,Sr)7(SiO3)6Cl2:Eu2+ phosphors, 69–72, 71–72f Sr3Al2O5Cl2:Eu2+ phosphors, 68–69, 70–71f, 70t Oxyhalides oxychlorides, 72–73, 73–74f oxyfluorides Ca8Mg(SiO4)4Cl2:Eu2+ phosphors, 67–68, 68–69f (Ca,Sr)7(SiO3)6Cl2:Eu2+ phosphors, 69–72, 71–72f Sr3Al2O5Cl2:Eu2+ phosphors, 68–69, 70–71f, 70t Oxysulfides AEGa2S4:Eu2+ (AE1⁄4alkaline earth) phosphors, 64–67, 66–67f, 66t AES:Eu2+ (AE1⁄4Ca and Sr) phosphors, 63, 64f Sr8Al12O24S2:Eu2+ phosphors, 64, 65f Peralkaline rock-associated deposits alkaline granites, 196–197 Dubbo deposit, 197 Nechalacho deposit, 196 nepheline syenites, 196 Round Top deposit, 197 Strange Lake deposits, 197 Percolation, 330 Placer deposits, 200–201, 201t Q Quantum critical regime, 297 Quantum critical theory definition, critical exponents, 295–296, 296t Ising model, 297–298 Landau mean field theory, 298 quantum phase transition, 297, 298f transverse field Ising model, 299 upper critical dimension, 299 Quantum critical wedge, 301 Quantum dots (QDs), 328, 348 Quantum ferroelectrics, 328 Quantum phase transition (QPT) Bose–Einstein condensation, magnons, 327 Ce(Cu,Au)6 Au-concentration tuning, 307 electrical resistivity, 309, 310f magnetic susceptibility, 307–308, 309f non-Fermi liquid (NFL) properties, 311 spin density wave (SDW), 309 spin fluctuations, 310 thermodynamic property, 307–308 CeCoIn5 antiferromagnetism (AFM), 319, 321f nuclear quadrupole resonance (NQR), 319 temperature–pressure phase diagram, 319, 320f CeIrIn5, 323 CeRhIn5 magnetic field, temperature, and pressure phase diagram, 321, 322f pressure induced superconductivity, 320–321, 322f classical continuous phase transitions (CPTs) concept of universality, 297 definition, critical exponents, 295–296, 296t first order, 294 order parameter, 295 reduced temperature, 294–295PDF Image | HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS
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