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HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS

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HANDBOOK ON THE PHYSICS AND CHEMISTRY OF RARE EARTHS ( handbook-onphysics-and-chemistry-rare-earths )

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Index 431 weathering carbonatites, 166–167 lateritic profile and behavior, 165–166 Great Oxidation Event (GOE), 182 Green-emitting phosphors (oxy)nitrides AESi2O2N2:Eu2+ (AE1⁄4Ca, Sr, and Ba), 48–51, 49t, 49–50f, 51t b-SiAlON:Eu2+, 46–48, 47–48f Y4Si2O7N2:Ce3+, 51–54, 52f, 52–53t, 54f oxides Ba2MgSi2O7:Eu2+, 31–34, 32–34f, 33t Ba9Sc2Si6O24:Eu2+, 34–35, 35–36f CaSc2O4:Ce3+, 29–31, 30–31f Ca3Sc2Si3O12:Ce3+, 28–29, 28–29f H Halides, 87–88 Hertz–Millis (HM) theory, itinerant magnets antiferromagnetism (AFM), 302 cerium-based compounds, 302 Gr€uneisen ratio, 303, 303f quantum critical wedge, 301 renormalization group theory, 300–301 spin-density wave (SDW), 300 superconducting dome, 303 Hydrothermal vein deposits, 198 Hyperscaling relation, 296 I Ion-adsorption type deposits alkaline and calc-alkaline granitic rocks, 200 allanite and titanite, 216–217 clays, 224–225 complexes, 222–224 denudation/preservation, 226–227 distribution map, 203, 205f fluorocarbonates, 216 geochemistry, parent granites characteristics, 211–214t geologic map, 206–208, 207–208f Heling deposits, 209 SiO2 contents, 210–216 Zhaibeiding granites, 208–209 Zudong muscovite granite, 207–208, 209f K€oppen–Geiger climate classification, 203, 204f leaching, 203–206, 205f mobility and fractionation accumulation zone, 220–221, 221f Ce anomalies vs. PERs, 220–221, 222f classification criteria, 219, 220f degree of weathering, 219 enriched zone, 220–221 vertical variation, 219 monazite, 218 phosphates, 217–218 projects, 199–200 surface weathering, 199 weathering, 203, 206 zircon, 218 Iron oxide–apatite (IOA) deposits, 197–198 Ising model Li(HoY)F4, 306–307 quantum critical theory, 297–298 J Josephson–junction arrays, 329 K Kondo theory breakdown, 317 L Lanthanides, luminescent thermometry advantages, 343–347t applications, 343–347t aromatic organic ligands, 385, 386f challenges, 405–406 classification, 351, 351f crystals, ionic complexes, 387–388 disadvantages, 343–347t emission approach, 352 energy levels, 351–352, 352f lifetime-based sensing methods, 353 light harvesting ligands, 384, 385f limitations, 342 maximum thermal sensitivity values, 404f, 405 metal-organic frameworks absolute sensitivity, 396 advantage, 395 postfunctionalization method, 396–397 ratiometric mixed lanthanide-organic dye thermometers, 396 self referencing thermometers, 395–396 molecular thermometers advantage, 388–389 inorganic matrices, 392 organic–inorganic hybrid matrices, 392–394 polymer matrices, 389–392

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