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--~ . ' .', ' ~- The structure of this stable high temperature form was unknown until very recently. Some doubt has been :raised whether the molecular unit was s8• However, preliminary results of a recent study (50) indicate that the structure is simila:r: to that of-orthorhombic (ex), except for the presence of.disordered sites, ,in which the molecules, at random, can assume a normal or an upside-down-~osition. Some mechani.cal properties (51) of s have recently been studied, and 13 heat capacity, heat conductivity and some electric constants are available. The IR spectrum is also known. - ' . .. (c) Monoclin~c (~) Sulphur The mother-of-pearl sulphur is well known. ) incomplete, and the' resistivity, p, for example, cannot be given more : precisely than 4xl620 ± (103) D em at r5~C. (b) .M::moclinic ([3) sulphur If a sulphur melt crysta:Ll.izes, monoclinfc ((3) crystals form. Such ~~rystals can be grown to very big specimens. Below 95.4°C the crystals transform slowly in'J:;o the orthorhombic (ex) form with a heat 'of transition of 96 cal/mole, but the quenched crystals can be maintained at room temperature up.to a month. 1be density is 1.96 g/crn(, .the space ~roup P 21/a·- C~h and the lattice constants are, at 103°C_,(45), ' ~ .' It reportedly occurs even in nature, but its stability is still disruted. It is often prepared· D .' a 0 = 1 1 . 0 4 A 0 13 = 9 6 . 7 ° 0 -b =10.98 A 0 0 c =10.92 A 0 -17- from an undercooled melt or by slow crystallization in an alcoholic ammonium polysulfide solution which oxidizes in air at a temperature below 156C.PDF Image | ELEMENTAL SULPHUR
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