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CATHODE ACTIVE MATERIAL-COATED DISCRETE GRAPHENE SHEETS FOR LITHIUM

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CATHODE ACTIVE MATERIAL-COATED DISCRETE GRAPHENE SHEETS FOR LITHIUM ( cathode-active-material-coated-discrete-graphene-sheets-for- )

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(12)UnitedStatesPatent (10)PatentNo.: US9.203,084B2 Wangetal. (54) CATHODEACTIVEMATERIAL-COATED DISCRETE GRAPHENE SHEETS FOR LITHIUM BATTERIES AND PROCESS FOR PRODUCING SAME (71) Applicants:YanboWang,HuberHeights,OH(US); BorZ,Jang,Centervile,OH(US);Hui He,Beavercreek,OH (US);Aruna Zhamu,Centervile,OH(US) (72) Inventors:YanboWang,HuberHeights,OH(US); BorZ,Jang,Centervile,OH(US);Hui He,Beavercreek,OH (US);Aruna Zhamu,Centervile,OH (US) (73) Assignee: NanotekInstrurments,Inc.,Dayton, OH(US) (*) Notice: Subjecttoanydisclaimer,thetermofthis patentisextendedoradjustedunder35 U.S.C.154(b)by179days. (21) Appl.No.:13/987,567 (22)Filed: Aug.8,2013 (65) Prior Publication Data (45)DateofPatent: Dec.1,2015 US 2015/OO44556A1 (51) Int.Cl. HOLM 4/36 HOLM 4/04 HOIM 4/O2 HOIM IO/O56 Feb. 12,2015 (2006.01) (2006.01) (2006.01) (2010.01) (52) U.S.Cl. CPC .H01M 4/366(2013.01);H01M 4/04 (2013.01);H0IM4/0421(2013.01):HOIM 10/056(2013.01);HOIM2004/028(2013.01) (58) FieldofClasificationSearch CPC .H01M6/00; H01M 10/00; H01M 10/04; HO1M 4/625 3:3:38:8:8 (56) USPC .429/217,212,231.8,231.7,219,405 Seeaplicationfileforcompletesearchhistory. ReferencesCited U.S.PATENTDOCUMENTS 7,824,651B2 11/2010 Zhamuetal. 8,236,446B2* 8/2012 Lu .429,209 US009203O84B2 8,765,302B2* 7/2014Chenetal.... 2011/O165466A1* 7,2011 Zhamuetal.. 2013/0323,603 A1* 12/2013 Ryuetal.... 2014/0013588A1* 1/2014Wangetal.. 2014/0141328A1* 5,2014Daietal..429,217 OTHER PUBLICATIONS Y.Ding,etal."Preparationofnano-structuredLiFePO4,graphene compositesbyco-precipitationmethod.”ElectrochemistryCommu nications12(2010)10-13. *citedbyexaminer PrimaryExaminer— NinaBhat (57) ABSTRACT Providedisacathode(positiveelectrode)ofalithiumbatery andaprocessforproducingthiscathode.Theelectrodecom prisesacathodeactivematerial-coatedgraphenesheetand the graphene shet has two opposed paralel Surfaces, whereinatleast50%area(preferablygreaterthan80%)of oneofthetwoSurfacesiscoatedwithacathodeactivemate rialcoating.Thegraphenematerialisinanamountoffrom 0.1%to99.5%byweightandthecathodeactivematerialisin anamountofatleast0.5%byweight(preferablygreaterthan 80%andmorepreferablygreaterthan90%),albasedonthe totalweightofthegraphenematerialandthecathodeactive materialcombined.Thecathodeactivematerialispreferably aninorganicmaterial,anorganicorpolymericmaterial,a metaloxide/phosphate/sulfide,oracombinationthereof. Alsoprovidedisalithiumbatery,includingalithium-ion, lithium-metal,orlithium-sulfurbatery. 35Claims,10DrawingSheets 38:::::::::::::::38x: .429,219 429,231.8 .429/320 .29.623.2

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