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Chapter 6: EIS and low temperature studies (a) (b) (c) (d) Figure 6-25. Fitting parameters of MF and LF semicircles: bulk electrode (b), Li/electrolyte interphase (c) and polysulfides/carbon interface (d) response recorded during 2nd and 3rd cycle. Evolution of resistance (colored line) and capacitance (black line) are shown, together with the voltage profile (a). It can be seen that the resistance of the electrode bulk (RNwC) is again, in a zoomed view, slightly evolving. Similar to what have been observed in the 1st cycle, large variations of the capacitance values are visible, and mostly at the end of discharge. The error values were not included on this graph, however, they were also high (even up to 50 – 60 % for the points recorded at fully discharged state). 221PDF Image | Accumulateur Lithium Soufre
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