Accumulateur Lithium Soufre

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Accumulateur Lithium Soufre ( accumulateur-lithium-soufre )

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(a) (b) Figure 5-22. Surface area evolution of Li2S (111) peak during 5th (a) and 6th (b) cycle at C/8. β-S8 appearance and disappearance is also marked (in red). In the next step, we compared the integrated surface area of the most intense (111) reflection of Li2S recorded at the end of discharge with the capacity of lower discharge plateau for both C rates (C/20 and C/8), bearing in mind that the final amount of Li2S formed at the end of discharge is interrupted by Li2S2 formation, according to the previous detailed discussion (section 5.4). Doing so, we observe rather linear behavior (Figure 5-23a), indicating that the C- rate (at least for moderate values) does not have a significant influence on the total (for both steps) efficiency of Li2S formation. We also compared the crystallite size obtained at the end of different cycle number and C-rates (Figure 5-23b). As they are relatively similar, this brings us to the conclusion that current density (C-rate) does not affect the crystallite size. (a) (b) Figure 5-23. Capacity corresponding to the lower discharge plateau, obtained at both C-rates, i.e. C/20 and C/8, plotted vs. Li2S (111) peak surface area, recorded at the end of discharge (a). Summary of the crystallite size calculated for both C-rates and during several cycles (b). Chapter 5: In situ and operando XRD 189

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