A lithium-sulfur battery with a solution-mediated pathway

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A lithium-sulfur battery with a solution-mediated pathway ( a-lithium-sulfur-battery-with-solution-mediated-pathway )

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a 2.4 2.2 2.0 1.8 0 0 Li E_G2_0.10 M Li2S4ACFC_Li2S8 LiE_G2_0.25M Li2S4ACFC_Li2S8 Li E_G2_0.50 M Li2S4ACFC_Li2S8 Li E_G2_0.75 M Li2S4ACFC_Li2S8 b 2.4 2.2 2.0 1.8 Li E_DOL/DME ACFC_Li2S8 LiE_G2ACFC_Li2S8 Li E_G2_0.5 M Li2S4ACFC_Li2S8 c 2.4 2.2 2.0 1.8 Li E_G2_0.50 M Li2S4ACFC_Li2S8 Li E_G2_0.33 M Li2S6ACFC_Li2S8 Li E_G2_0.25 M Li2S8ACFC_Li2S8 d 0.5 0.0 -0.5 -1.0 -1.5 -2.0 -2.5 2.09 0 400 800 1200 1600 2000 Sulfur loading: 6 mg cm-2 E/Scathode ratio: 3.0; 30oC 400 800 1200 1600 ) 0 400 Sulfur loading: 6 mg cm-2 E/Scathode ratio: 3.0; 30oC 800 1200 1600 ) Specific capacity (mAh g-1 s_ cathode Specific capacity (mAh g-1 ) s_total 400 800 1200 Specific capacity (mAh g-1 s_ cathode Sulfur loading: 6 mg cm-2 E/Scathode ratio: 3.0; 30oC 1.83 1.8 1.95 1.90 2.13 Potential (Vvs.Li/Li+) Potential (Vvs.Li/Li+) Q (mAh) Potential (V vs. Li/Li+) Specific capacity (mAh g-1 s_cathode ) Figure 2 ǀ Li2S4-retention dependence on sulfur utilization. Electrolyte dependence of the typical discharge capacity for Li-S cells using ACFC-Li2S8 as the cathode with a sulfur loading of 6 mg cm−2 at an E/Scathode ratio of 3.0 mLE g represents the weight of sulfur in cathode. (a) using different concentrations of Li2S4 in Z; (b) using E_DOL/DME(1 M LiTFSI_0.3 M LiNO3 in DOL/DME), E_G2, and E_G2_0.50 M Li2S4; (c) using different concentrations of LiPS with 2 M [S] in Z; (d) PCGA curves for the discharge of two Li-S cells with different electrolytes. Page 16 of 24 S_cathode −1, 0.12 mA cm−2, and 30 °C. The gs_cathode 1.85 Li E_DOL/DME ACFC_Li2S8 LiE_G2_0.5MLi2S4ACFC_Li2S8 2.0 2.2 2.4 Potential (V) vs. Li/Li+

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